[Mo2(CCH)4(PMe3)4], the Parent Dimetallapolyyne
A π(CC)‐δ(MM)‐π(CC) electron framework exists in the title compound 1, the simplest complex of the type [M2(CCR)4(PMe3)4], and the first to be characterized by X‐ray crystallography. This dimetallapolyyne differs from the more highly substituted derivatives in its electronic properties; however, in...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie (International ed.) 1993-03, Vol.32 (3), p.409-411 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 411 |
|---|---|
| container_issue | 3 |
| container_start_page | 409 |
| container_title | Angewandte Chemie (International ed.) |
| container_volume | 32 |
| creator | Stoner, Timothy C. Geib, Steven J. Hopkins, Michael D. |
| description | A π(CC)‐δ(MM)‐π(CC) electron framework exists in the title compound 1, the simplest complex of the type [M2(CCR)4(PMe3)4], and the first to be characterized by X‐ray crystallography. This dimetallapolyyne differs from the more highly substituted derivatives in its electronic properties; however, in several instances, the properties of 1 closely parallel its nearest organic analogue, the tetraethynylethene C10H14. L = PMe3. |
| doi_str_mv | 10.1002/anie.199304091 |
| format | Article |
| fullrecord | <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_anie_199304091</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_WNG_X01G6FXK_M</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3561-ef45be35c325aa5106872ac1cd87d7034b03eee3a2520e2db112ee15d7003ba53</originalsourceid><addsrcrecordid>eNqFj89Lw0AQhRdRsFavnnvw0IKpszvZbHIssb-wrT0oFkSWTTrBaJqW3YDmv7clUrx5msP7vjc8xq459DmAuDNlTn0eRQg-RPyEtbgU3EOl8JS1QCrwIEQ8ZxfOfez5MISgxe5e51vRjeNJz-8u54Q9_-22U71TZ2kslVXnPt9QZYrC7LZFXZd0yc4yUzi6-r1t9jwaPsUTb_Y4nsaDmZeiDLhHmS8TQpmikMZIDkGohEl5ug7VWgH6CSARoRFSAIl1wrkg4nKfASZGYpv1m97Ubp2zlOmdzTfG1pqDPszVh7n6OHcv3DTCzrjUFJk1ZZq7o-WrUApxwKIG-8oLqv8p1YPFdPj3hde4uavo--ga-6kDhUrql8VYr4CPg9HqQc_xB7yFckI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>[Mo2(CCH)4(PMe3)4], the Parent Dimetallapolyyne</title><source>Wiley Journals</source><creator>Stoner, Timothy C. ; Geib, Steven J. ; Hopkins, Michael D.</creator><creatorcontrib>Stoner, Timothy C. ; Geib, Steven J. ; Hopkins, Michael D.</creatorcontrib><description>A π(CC)‐δ(MM)‐π(CC) electron framework exists in the title compound 1, the simplest complex of the type [M2(CCR)4(PMe3)4], and the first to be characterized by X‐ray crystallography. This dimetallapolyyne differs from the more highly substituted derivatives in its electronic properties; however, in several instances, the properties of 1 closely parallel its nearest organic analogue, the tetraethynylethene C10H14. L = PMe3.</description><identifier>ISSN: 0570-0833</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.199304091</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Zug: Hüthig & Wepf Verlag</publisher><subject>Chemistry ; Condensed matter: structure, mechanical and thermal properties ; Coordination compounds ; Exact sciences and technology ; Inorganic chemistry and origins of life ; Inorganic compounds ; Metal complexes ; Physics ; Preparations and properties ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Angewandte Chemie (International ed.), 1993-03, Vol.32 (3), p.409-411</ispartof><rights>Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany</rights><rights>1993 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3561-ef45be35c325aa5106872ac1cd87d7034b03eee3a2520e2db112ee15d7003ba53</citedby><cites>FETCH-LOGICAL-c3561-ef45be35c325aa5106872ac1cd87d7034b03eee3a2520e2db112ee15d7003ba53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.199304091$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.199304091$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4785221$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Stoner, Timothy C.</creatorcontrib><creatorcontrib>Geib, Steven J.</creatorcontrib><creatorcontrib>Hopkins, Michael D.</creatorcontrib><title>[Mo2(CCH)4(PMe3)4], the Parent Dimetallapolyyne</title><title>Angewandte Chemie (International ed.)</title><addtitle>Angew. Chem. Int. Ed. Engl</addtitle><description>A π(CC)‐δ(MM)‐π(CC) electron framework exists in the title compound 1, the simplest complex of the type [M2(CCR)4(PMe3)4], and the first to be characterized by X‐ray crystallography. This dimetallapolyyne differs from the more highly substituted derivatives in its electronic properties; however, in several instances, the properties of 1 closely parallel its nearest organic analogue, the tetraethynylethene C10H14. L = PMe3.</description><subject>Chemistry</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Coordination compounds</subject><subject>Exact sciences and technology</subject><subject>Inorganic chemistry and origins of life</subject><subject>Inorganic compounds</subject><subject>Metal complexes</subject><subject>Physics</subject><subject>Preparations and properties</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>0570-0833</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNqFj89Lw0AQhRdRsFavnnvw0IKpszvZbHIssb-wrT0oFkSWTTrBaJqW3YDmv7clUrx5msP7vjc8xq459DmAuDNlTn0eRQg-RPyEtbgU3EOl8JS1QCrwIEQ8ZxfOfez5MISgxe5e51vRjeNJz-8u54Q9_-22U71TZ2kslVXnPt9QZYrC7LZFXZd0yc4yUzi6-r1t9jwaPsUTb_Y4nsaDmZeiDLhHmS8TQpmikMZIDkGohEl5ug7VWgH6CSARoRFSAIl1wrkg4nKfASZGYpv1m97Ubp2zlOmdzTfG1pqDPszVh7n6OHcv3DTCzrjUFJk1ZZq7o-WrUApxwKIG-8oLqv8p1YPFdPj3hde4uavo--ga-6kDhUrql8VYr4CPg9HqQc_xB7yFckI</recordid><startdate>199303</startdate><enddate>199303</enddate><creator>Stoner, Timothy C.</creator><creator>Geib, Steven J.</creator><creator>Hopkins, Michael D.</creator><general>Hüthig & Wepf Verlag</general><general>VCH</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199303</creationdate><title>[Mo2(CCH)4(PMe3)4], the Parent Dimetallapolyyne</title><author>Stoner, Timothy C. ; Geib, Steven J. ; Hopkins, Michael D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3561-ef45be35c325aa5106872ac1cd87d7034b03eee3a2520e2db112ee15d7003ba53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Chemistry</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Coordination compounds</topic><topic>Exact sciences and technology</topic><topic>Inorganic chemistry and origins of life</topic><topic>Inorganic compounds</topic><topic>Metal complexes</topic><topic>Physics</topic><topic>Preparations and properties</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stoner, Timothy C.</creatorcontrib><creatorcontrib>Geib, Steven J.</creatorcontrib><creatorcontrib>Hopkins, Michael D.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stoner, Timothy C.</au><au>Geib, Steven J.</au><au>Hopkins, Michael D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>[Mo2(CCH)4(PMe3)4], the Parent Dimetallapolyyne</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><addtitle>Angew. Chem. Int. Ed. Engl</addtitle><date>1993-03</date><risdate>1993</risdate><volume>32</volume><issue>3</issue><spage>409</spage><epage>411</epage><pages>409-411</pages><issn>0570-0833</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>A π(CC)‐δ(MM)‐π(CC) electron framework exists in the title compound 1, the simplest complex of the type [M2(CCR)4(PMe3)4], and the first to be characterized by X‐ray crystallography. This dimetallapolyyne differs from the more highly substituted derivatives in its electronic properties; however, in several instances, the properties of 1 closely parallel its nearest organic analogue, the tetraethynylethene C10H14. L = PMe3.</abstract><cop>Zug</cop><pub>Hüthig & Wepf Verlag</pub><doi>10.1002/anie.199304091</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0570-0833 |
| ispartof | Angewandte Chemie (International ed.), 1993-03, Vol.32 (3), p.409-411 |
| issn | 0570-0833 1521-3773 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_anie_199304091 |
| source | Wiley Journals |
| subjects | Chemistry Condensed matter: structure, mechanical and thermal properties Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Metal complexes Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | [Mo2(CCH)4(PMe3)4], the Parent Dimetallapolyyne |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-05T09%3A31%3A37IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=%5BMo2(CCH)4(PMe3)4%5D,%20the%20Parent%20Dimetallapolyyne&rft.jtitle=Angewandte%20Chemie%20(International%20ed.)&rft.au=Stoner,%20Timothy%20C.&rft.date=1993-03&rft.volume=32&rft.issue=3&rft.spage=409&rft.epage=411&rft.pages=409-411&rft.issn=0570-0833&rft.eissn=1521-3773&rft.coden=ACIEAY&rft_id=info:doi/10.1002/anie.199304091&rft_dat=%3Cistex_cross%3Eark_67375_WNG_X01G6FXK_M%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |