Fluorescence "Off-On" Signalling upon Linear Recognition and Binding of α,ω-Alkanediyldiammonium Ions by 9,10-Bis{(1-aza-4,7,10,13,16-pentaoxacyclooctadecyl)methyl}anthracene

Fluorescence "Off-On" Signalling upon Linear Recognition and Binding of α,ω-Alkanediyldiammonium Ions by 9,10-Bis{(1-aza-4,7,10,13,16-pentaoxacyclooctadecyl)methyl}anthracene

No Absract. A drastic increase in the fluorescence quantum yield is observed when 1, which contains two crown ether units and a rigid fluorescing spacer, is allowed to react with an α,ω‐alkanediyldiammonium ion of the “correct” chain length. Most effective is the pseudointramolecular cyclization whe...

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Veröffentlicht in:Angewandte Chemie International Edition 1990-10, Vol.29 (10), p.1173-1175
Hauptverfasser: de Silva, A. Prasanna, Sandanayake, K. R. A. Samankumara
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description No Absract. A drastic increase in the fluorescence quantum yield is observed when 1, which contains two crown ether units and a rigid fluorescing spacer, is allowed to react with an α,ω‐alkanediyldiammonium ion of the “correct” chain length. Most effective is the pseudointramolecular cyclization when the alkanediyldiammonium ion has a C4 chain.
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title Fluorescence "Off-On" Signalling upon Linear Recognition and Binding of α,ω-Alkanediyldiammonium Ions by 9,10-Bis{(1-aza-4,7,10,13,16-pentaoxacyclooctadecyl)methyl}anthracene
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