Cycloaddition Reactions of CpCo-Stabilized Cyclobutadiene Derivatives

Cycloaddition Reactions of CpCo-Stabilized Cyclobutadiene Derivatives

The pyridine derivative 3 is unexpectedly formed upon reaction of the cyclodecadiyne 1 and glutaronitrile 2 in the presence of CpCo(CO)2 as catalyst. Formally this must involve opening of a CC bond of 1. The formation of 3 can be explained in terms of an equilibrium, in which, inter alia, cobaltacy...

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Veröffentlicht in:Angewandte Chemie International Edition 1990-03, Vol.29 (3), p.276-279
Hauptverfasser: Gleiter, Rolf, Kratz, Detlef
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creator Gleiter, Rolf
Kratz, Detlef
description The pyridine derivative 3 is unexpectedly formed upon reaction of the cyclodecadiyne 1 and glutaronitrile 2 in the presence of CpCo(CO)2 as catalyst. Formally this must involve opening of a CC bond of 1. The formation of 3 can be explained in terms of an equilibrium, in which, inter alia, cobaltacyclopentadiene and surprisingly the title compounds participate.
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title Cycloaddition Reactions of CpCo-Stabilized Cyclobutadiene Derivatives
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