A Systematic Entry to Butterfly-Type [M4(CO)12(μ4-XY)] Clusters

A Systematic Entry to Butterfly-Type [M4(CO)12(μ4-XY)] Clusters

The photochemical generation of M(CO)3 fragments from simple carbonyl complexes and their addition to X = Y‐bridged trinuclear clusters provides a general route to tetranuclear clusters having butterfly structures. The detailed structure depends on the kind of unsaturated ligands XY and their electr...

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Veröffentlicht in:Angewandte Chemie International Edition 1989-08, Vol.28 (8), p.1059-1060
Hauptverfasser: Bantel, Harald, Hansert, Bernhard, Powell, Anne K., Tasi, Miklos, Vahrenkamp, Heinrich
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container_issue 8
container_start_page 1059
container_title Angewandte Chemie International Edition
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creator Bantel, Harald
Hansert, Bernhard
Powell, Anne K.
Tasi, Miklos
Vahrenkamp, Heinrich
description The photochemical generation of M(CO)3 fragments from simple carbonyl complexes and their addition to X = Y‐bridged trinuclear clusters provides a general route to tetranuclear clusters having butterfly structures. The detailed structure depends on the kind of unsaturated ligands XY and their electron count (see picture). Such a cluster expansion should change the reactivity of the ligands XY, thereby allowing preparatively useful transformations.
doi_str_mv 10.1002/anie.198910591
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title A Systematic Entry to Butterfly-Type [M4(CO)12(μ4-XY)] Clusters
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