Carbanions as Intermediates in the Synthesis of Grignard Reagents

Evidence for the occurrence of R⊖ in reaction (a) is provided by the isolation of compounds such as 2 in the reaction of 1 with Mg in THF after addition of Me3GeCl. On the basis of a series of comparative experiments it could be concluded that a carbanion intermediate is probably responsible for the...

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Veröffentlicht in:	Angewandte Chemie International Edition 1988-05, Vol.27 (5), p.687-689
Hauptverfasser:	de Boer, Henricus J. R., Akkerman, Otto S., Bickelhaupt, Friedrich
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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