A New Route to Nitrile Oxides via α-Nitrosodiazo Derivatives

A New Route to Nitrile Oxides via α-Nitrosodiazo Derivatives

The analogy between a 1,2‐bis(carbenoid) species and a species containing a triple bond, |CNO↔CN→O|, was the basis for the method shown below for the synthesis of nitrile oxides. Noteworthy is the direct introduction of the NO group. Compound 1 is also the first nitrile oxide containing a P‐bou...

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Veröffentlicht in:Angewandte Chemie International Edition 1988-02, Vol.27 (2), p.301-302
Hauptverfasser: Sicard, Ghislaine, Baceiredo, Antoine, Crocco, Guy, Bertrand, Guy
Format: Artikel
Sprache:eng
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Zusammenfassung:The analogy between a 1,2‐bis(carbenoid) species and a species containing a triple bond, |CNO↔CN→O|, was the basis for the method shown below for the synthesis of nitrile oxides. Noteworthy is the direct introduction of the NO group. Compound 1 is also the first nitrile oxide containing a P‐bound CNO group (R = iPr2N).
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.198803011