The Copolymer of 2,6-Pyridinedimethanethiol and 1,4-Benzenedimethanethiol

The Copolymer of 2,6-Pyridinedimethanethiol and 1,4-Benzenedimethanethiol

The first polymer containing pyridinc rings as part of the backbone chain, the title compound 3, was prepared from the two bis(chloromethyl) compounds 1 and 2 and Na2S. 3 is insoluble, but melts (m.p. = 177°C) and can undergo extrusion to produce films. With Na2S alone, 1 forms a cyclic tetramer.

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Veröffentlicht in:Angewandte Chemie International Edition 1987-02, Vol.26 (2), p.137-139
Hauptverfasser: Modica, Giovanni, Maffi, Silvia, Mantoneri, Enzo, Giuffré, Luigi, Grassi, Antonio
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container_end_page 139
container_issue 2
container_start_page 137
container_title Angewandte Chemie International Edition
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creator Modica, Giovanni
Maffi, Silvia
Mantoneri, Enzo
Giuffré, Luigi
Grassi, Antonio
description The first polymer containing pyridinc rings as part of the backbone chain, the title compound 3, was prepared from the two bis(chloromethyl) compounds 1 and 2 and Na2S. 3 is insoluble, but melts (m.p. = 177°C) and can undergo extrusion to produce films. With Na2S alone, 1 forms a cyclic tetramer.
doi_str_mv 10.1002/anie.198701371
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