Synthesis of Diindenyldivanadium-a New Variant of the Reductive Degradation of Metallocenes and Related Compounds
A V2 structural unit that is coordinated to all the C atoms of two sandwiching indenyl ligands characterizes the title compound 2. This dark violet, paramagentic sandwich complex can be synthesizd by reduction of diindenylvanadium 1 with potassium in tetrahydrofuran. The V‐V distance in 2 is 2.351(1...
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| Veröffentlicht in: | Angewandte Chemie International Edition 1986-10, Vol.25 (10), p.928-929 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A V2 structural unit that is coordinated to all the C atoms of two sandwiching indenyl ligands characterizes the title compound 2. This dark violet, paramagentic sandwich complex can be synthesizd by reduction of diindenylvanadium 1 with potassium in tetrahydrofuran. The V‐V distance in 2 is 2.351(1) Å. |
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| ISSN: | 0570-0833 1521-3773 |
| DOI: | 10.1002/anie.198609281 |