The First Stable Derivative of 7-Stannanorbornane and Its Thermolysis
Free dimethylstannanediyl (“dimethylstannylene”) (2)—to be regarded as truly free because of its synthesis—has been generated by thermolysis of the adduct (1) which is stable at −30°C. A concerted mechanism is proposed to account for the formation of (2).
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| Veröffentlicht in: | Angewandte Chemie International Edition 1979-07, Vol.18 (7), p.543-544 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Free dimethylstannanediyl (“dimethylstannylene”) (2)—to be regarded as truly free because of its synthesis—has been generated by thermolysis of the adduct (1) which is stable at −30°C. A concerted mechanism is proposed to account for the formation of (2). |
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| ISSN: | 0570-0833 1521-3773 |
| DOI: | 10.1002/anie.197905431 |