Extension of the Scope of Anionic Cycloadditions by Activating Organoelement Groups

Activation of olefins in the anionic cycloaddition of 2‐azaallyl compounds such as (1) can be accomplished by the organoelement groups SPh, SePh, PPh2 and AsPh2. They can be removed from the cycloadducts (2) with relative ease.

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Veröffentlicht in:Angewandte Chemie International Edition 1977-02, Vol.16 (2), p.119-119
Hauptverfasser: Kauffmann, Thomas, Ahlers, Holger, Hamsen, Angelika, Schulz, Herbert, Tilhard, Hans-Joachim, Vahrenhorst, Annemarie
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container_end_page 119
container_issue 2
container_start_page 119
container_title Angewandte Chemie International Edition
container_volume 16
creator Kauffmann, Thomas
Ahlers, Holger
Hamsen, Angelika
Schulz, Herbert
Tilhard, Hans-Joachim
Vahrenhorst, Annemarie
description Activation of olefins in the anionic cycloaddition of 2‐azaallyl compounds such as (1) can be accomplished by the organoelement groups SPh, SePh, PPh2 and AsPh2. They can be removed from the cycloadducts (2) with relative ease.
doi_str_mv 10.1002/anie.197701191
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title Extension of the Scope of Anionic Cycloadditions by Activating Organoelement Groups
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