High-temperature Chlorination of Amines and Acylamines

High-temperature Chlorination of Amines and Acylamines

High‐temperature chlorination of acyl derivatives of primary and secondary amines and of tertiary alkyl amines usually yields compounds containing either the imidochloride (monochloromethyleneamino) group or the dichloroisocyanide (dichloromethyleneamino) group . In many cases, yields in the range o...

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Veröffentlicht in:Angewandte Chemie International Edition 1962-12, Vol.1 (12), p.632-639
1. Verfasser: Holtschmidt, H.
Format: Artikel
Sprache:eng
Schlagworte:
Acyl amines
Amines
Chlorination
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Beschreibung
Zusammenfassung:High‐temperature chlorination of acyl derivatives of primary and secondary amines and of tertiary alkyl amines usually yields compounds containing either the imidochloride (monochloromethyleneamino) group or the dichloroisocyanide (dichloromethyleneamino) group . In many cases, yields in the range of 80 to 95% are obtaied. Several ring‐opening and ring‐closing reactions ocurring under the conditions of high‐temperature chlorination ae described.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.196206321