Innentitelbild: Facile Energy Release from Substituted Dewar Isomers of 1,2‐Dihydro‐1,2‐Azaborinines Catalyzed by Coinage Metal Lewis Acids (Angew. Chem. 30/2024)

Coinage metals catalyze energy release from the Dewar isomer of 1,2‐dihydroazaborinine—a promising molecular solar thermal (MOST) storage system, as shown by Holger F. Bettinger, Ivana Fleischer and co‐workers in their Research Article (e202405818). Mechanistic studies corroborated by computations provide insights into the catalytic system, while showcasing the first crystal structure of the energy‐rich Dewar dihydroazaborinine isomer coordinated to Ag(I).