Elevating Discharge Voltage of Li 2 CO 3 ‐Routine Li−CO 2 Battery over 2.9 V at an Ultra‐Wide Temperature Window
The Li−CO 2 batteries utilizing greenhouse gas CO 2 possess advantages of high energy density and environmental friendliness. However, these batteries following Li 2 CO 3 ‐product route typically exhibit low work voltage (
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| Veröffentlicht in: | Angewandte Chemie 2024-08, Vol.136 (34) |
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| container_title | Angewandte Chemie |
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| creator | Zhao, Ning Liu, Limin Lu, Xuan Li, Yuyang Wu, Xiaosha Peng, Shaochen Wei, Jingwen Gao, Yang Zhang, Hanqi Fan, Yiming Yin, Zicheng Feng, Rongfen Wang, Ru Hu, Xiaofei Ding, Shujiang Liu, Wenfeng |
| description | The Li−CO
2
batteries utilizing greenhouse gas CO
2
possess advantages of high energy density and environmental friendliness. However, these batteries following Li
2
CO
3
‐product route typically exhibit low work voltage ( |
| doi_str_mv | 10.1002/ange.202407303 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1002_ange_202407303</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1002_ange_202407303</sourcerecordid><originalsourceid>FETCH-crossref_primary_10_1002_ange_2024073033</originalsourceid><addsrcrecordid>eNqVj8FKw0AURQepYKpuXb8fSHyZSY3ZWisuBEFquxwe7UscSTNlZlrtrhvBpfiJ-RKnIO5dXTjcszhCXOSY5YjykrqGM4mywFKhOhJJPpJ5qspRORAJYlGk17KoTsTQ-1dEvJJllYj3SctbCqZr4Nb4xQu5hmFm20BxbQ0PBiSMH0FBv_96spv45Aj7z-8IJdxQCOx2YLfsQGZVv_-YAQWgDp7b4ChKc7NkmPJqzY7CxjHMTbe0b2fiuKbW8_nvnorsbjId36cLZ713XOu1MytyO52jPvTpQ5_-61P_Fn4AYYZalw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Elevating Discharge Voltage of Li 2 CO 3 ‐Routine Li−CO 2 Battery over 2.9 V at an Ultra‐Wide Temperature Window</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Zhao, Ning ; Liu, Limin ; Lu, Xuan ; Li, Yuyang ; Wu, Xiaosha ; Peng, Shaochen ; Wei, Jingwen ; Gao, Yang ; Zhang, Hanqi ; Fan, Yiming ; Yin, Zicheng ; Feng, Rongfen ; Wang, Ru ; Hu, Xiaofei ; Ding, Shujiang ; Liu, Wenfeng</creator><creatorcontrib>Zhao, Ning ; Liu, Limin ; Lu, Xuan ; Li, Yuyang ; Wu, Xiaosha ; Peng, Shaochen ; Wei, Jingwen ; Gao, Yang ; Zhang, Hanqi ; Fan, Yiming ; Yin, Zicheng ; Feng, Rongfen ; Wang, Ru ; Hu, Xiaofei ; Ding, Shujiang ; Liu, Wenfeng</creatorcontrib><description>The Li−CO
2
batteries utilizing greenhouse gas CO
2
possess advantages of high energy density and environmental friendliness. However, these batteries following Li
2
CO
3
‐product route typically exhibit low work voltage (<2.5 V) and energy efficiency. Herein, we have demonstrated for the first time that cobalt phthalocyanine (CoPc) as homogeneous catalyst can elevate the work plateau towards 2.98 V, which is higher than its theoretical discharge voltage without changing the Li
2
CO
3
‐product route. This unprecedented discharge voltage is illustrated by mass spectrum and electrochemical analyses that CoPc has powerful adsorption capability with CO
2
(−7.484 kJ mol
−1
) and forms discharge intermediate of C
33
H
16
CoN
8
O
2
. Besides high discharge capacity of 18724 mAh g
−1
and robust cyclability over 1600 hours (1000 mAh g
−1
cut‐off) at a current density of 100 mA g
−1
, the batteries show high temperature adaptability (−30–80 °C). Our work is paving a promising avenue for the progress of high‐efficiency Li−CO
2
batteries.</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.202407303</identifier><language>eng</language><ispartof>Angewandte Chemie, 2024-08, Vol.136 (34)</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-crossref_primary_10_1002_ange_2024073033</cites><orcidid>0000-0002-9924-2776</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Zhao, Ning</creatorcontrib><creatorcontrib>Liu, Limin</creatorcontrib><creatorcontrib>Lu, Xuan</creatorcontrib><creatorcontrib>Li, Yuyang</creatorcontrib><creatorcontrib>Wu, Xiaosha</creatorcontrib><creatorcontrib>Peng, Shaochen</creatorcontrib><creatorcontrib>Wei, Jingwen</creatorcontrib><creatorcontrib>Gao, Yang</creatorcontrib><creatorcontrib>Zhang, Hanqi</creatorcontrib><creatorcontrib>Fan, Yiming</creatorcontrib><creatorcontrib>Yin, Zicheng</creatorcontrib><creatorcontrib>Feng, Rongfen</creatorcontrib><creatorcontrib>Wang, Ru</creatorcontrib><creatorcontrib>Hu, Xiaofei</creatorcontrib><creatorcontrib>Ding, Shujiang</creatorcontrib><creatorcontrib>Liu, Wenfeng</creatorcontrib><title>Elevating Discharge Voltage of Li 2 CO 3 ‐Routine Li−CO 2 Battery over 2.9 V at an Ultra‐Wide Temperature Window</title><title>Angewandte Chemie</title><description>The Li−CO
2
batteries utilizing greenhouse gas CO
2
possess advantages of high energy density and environmental friendliness. However, these batteries following Li
2
CO
3
‐product route typically exhibit low work voltage (<2.5 V) and energy efficiency. Herein, we have demonstrated for the first time that cobalt phthalocyanine (CoPc) as homogeneous catalyst can elevate the work plateau towards 2.98 V, which is higher than its theoretical discharge voltage without changing the Li
2
CO
3
‐product route. This unprecedented discharge voltage is illustrated by mass spectrum and electrochemical analyses that CoPc has powerful adsorption capability with CO
2
(−7.484 kJ mol
−1
) and forms discharge intermediate of C
33
H
16
CoN
8
O
2
. Besides high discharge capacity of 18724 mAh g
−1
and robust cyclability over 1600 hours (1000 mAh g
−1
cut‐off) at a current density of 100 mA g
−1
, the batteries show high temperature adaptability (−30–80 °C). Our work is paving a promising avenue for the progress of high‐efficiency Li−CO
2
batteries.</description><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqVj8FKw0AURQepYKpuXb8fSHyZSY3ZWisuBEFquxwe7UscSTNlZlrtrhvBpfiJ-RKnIO5dXTjcszhCXOSY5YjykrqGM4mywFKhOhJJPpJ5qspRORAJYlGk17KoTsTQ-1dEvJJllYj3SctbCqZr4Nb4xQu5hmFm20BxbQ0PBiSMH0FBv_96spv45Aj7z-8IJdxQCOx2YLfsQGZVv_-YAQWgDp7b4ChKc7NkmPJqzY7CxjHMTbe0b2fiuKbW8_nvnorsbjId36cLZ713XOu1MytyO52jPvTpQ5_-61P_Fn4AYYZalw</recordid><startdate>20240819</startdate><enddate>20240819</enddate><creator>Zhao, Ning</creator><creator>Liu, Limin</creator><creator>Lu, Xuan</creator><creator>Li, Yuyang</creator><creator>Wu, Xiaosha</creator><creator>Peng, Shaochen</creator><creator>Wei, Jingwen</creator><creator>Gao, Yang</creator><creator>Zhang, Hanqi</creator><creator>Fan, Yiming</creator><creator>Yin, Zicheng</creator><creator>Feng, Rongfen</creator><creator>Wang, Ru</creator><creator>Hu, Xiaofei</creator><creator>Ding, Shujiang</creator><creator>Liu, Wenfeng</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-9924-2776</orcidid></search><sort><creationdate>20240819</creationdate><title>Elevating Discharge Voltage of Li 2 CO 3 ‐Routine Li−CO 2 Battery over 2.9 V at an Ultra‐Wide Temperature Window</title><author>Zhao, Ning ; Liu, Limin ; Lu, Xuan ; Li, Yuyang ; Wu, Xiaosha ; Peng, Shaochen ; Wei, Jingwen ; Gao, Yang ; Zhang, Hanqi ; Fan, Yiming ; Yin, Zicheng ; Feng, Rongfen ; Wang, Ru ; Hu, Xiaofei ; Ding, Shujiang ; Liu, Wenfeng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-crossref_primary_10_1002_ange_2024073033</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Ning</creatorcontrib><creatorcontrib>Liu, Limin</creatorcontrib><creatorcontrib>Lu, Xuan</creatorcontrib><creatorcontrib>Li, Yuyang</creatorcontrib><creatorcontrib>Wu, Xiaosha</creatorcontrib><creatorcontrib>Peng, Shaochen</creatorcontrib><creatorcontrib>Wei, Jingwen</creatorcontrib><creatorcontrib>Gao, Yang</creatorcontrib><creatorcontrib>Zhang, Hanqi</creatorcontrib><creatorcontrib>Fan, Yiming</creatorcontrib><creatorcontrib>Yin, Zicheng</creatorcontrib><creatorcontrib>Feng, Rongfen</creatorcontrib><creatorcontrib>Wang, Ru</creatorcontrib><creatorcontrib>Hu, Xiaofei</creatorcontrib><creatorcontrib>Ding, Shujiang</creatorcontrib><creatorcontrib>Liu, Wenfeng</creatorcontrib><collection>CrossRef</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Ning</au><au>Liu, Limin</au><au>Lu, Xuan</au><au>Li, Yuyang</au><au>Wu, Xiaosha</au><au>Peng, Shaochen</au><au>Wei, Jingwen</au><au>Gao, Yang</au><au>Zhang, Hanqi</au><au>Fan, Yiming</au><au>Yin, Zicheng</au><au>Feng, Rongfen</au><au>Wang, Ru</au><au>Hu, Xiaofei</au><au>Ding, Shujiang</au><au>Liu, Wenfeng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Elevating Discharge Voltage of Li 2 CO 3 ‐Routine Li−CO 2 Battery over 2.9 V at an Ultra‐Wide Temperature Window</atitle><jtitle>Angewandte Chemie</jtitle><date>2024-08-19</date><risdate>2024</risdate><volume>136</volume><issue>34</issue><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>The Li−CO
2
batteries utilizing greenhouse gas CO
2
possess advantages of high energy density and environmental friendliness. However, these batteries following Li
2
CO
3
‐product route typically exhibit low work voltage (<2.5 V) and energy efficiency. Herein, we have demonstrated for the first time that cobalt phthalocyanine (CoPc) as homogeneous catalyst can elevate the work plateau towards 2.98 V, which is higher than its theoretical discharge voltage without changing the Li
2
CO
3
‐product route. This unprecedented discharge voltage is illustrated by mass spectrum and electrochemical analyses that CoPc has powerful adsorption capability with CO
2
(−7.484 kJ mol
−1
) and forms discharge intermediate of C
33
H
16
CoN
8
O
2
. Besides high discharge capacity of 18724 mAh g
−1
and robust cyclability over 1600 hours (1000 mAh g
−1
cut‐off) at a current density of 100 mA g
−1
, the batteries show high temperature adaptability (−30–80 °C). Our work is paving a promising avenue for the progress of high‐efficiency Li−CO
2
batteries.</abstract><doi>10.1002/ange.202407303</doi><orcidid>https://orcid.org/0000-0002-9924-2776</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| title | Elevating Discharge Voltage of Li 2 CO 3 ‐Routine Li−CO 2 Battery over 2.9 V at an Ultra‐Wide Temperature Window |
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