Stereoselective Synthesis of Cyclohepta[b]indoles by Visible‐Light‐Induced [2+2]‐Cycloaddition/retro‐Mannich‐type Reactions

A novel method for the concise synthesis of cyclohepta[b]indoles in high yields was developed. The method involves a visible‐light‐induced, photocatalyzed [2+2]‐cycloaddition/ retro‐Mannich‐type reaction of enaminones. Experimental and computational studies suggested that the reaction is a photoredo...

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Veröffentlicht in:	Angewandte Chemie 2021-05, Vol.133 (20), p.11311-11316
Hauptverfasser:	Mu, Xin‐Peng, Li, Yuan‐He, Zheng, Nan, Long, Jian‐Yu, Chen, Si‐Jia, Liu, Bing‐Yan, Zhao, Chun‐Bo, Yang, Zhen
Format:	Artikel
Sprache:	eng
Schlagworte:	[2+2]/retro-Mannich-type cycloaddition amine radical cation cyclohepta[b]indole photoredox catalysis
Online-Zugang:	Volltext
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