Synthesis of Bis(alkenyl)oligosilanes via Double Hydrosilylation and Their Structures and Photophysical Properties

Synthesis of Bis(alkenyl)oligosilanes via Double Hydrosilylation and Their Structures and Photophysical Properties

A series of novel bis(alkenyl)oligosilanes was synthesized via ruthenium‐catalyzed double hydrosilylation of alkynes with dihydrooligosilanes. The structural and photophysical features of the bis(alkenyl)oligosilanes were studied by X‐ray crystallography and UV and fluorescence spectra. The function...

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Veröffentlicht in:Asian journal of organic chemistry 2024-12
Hauptverfasser: Kanno, Ken‐ichiro, Kajima, Keisuke, Suzuki, Yudai, Honma, Ryuya, Kyushin, Soichiro
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container_title Asian journal of organic chemistry
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creator Kanno, Ken‐ichiro
Kajima, Keisuke
Suzuki, Yudai
Honma, Ryuya
Kyushin, Soichiro
description A series of novel bis(alkenyl)oligosilanes was synthesized via ruthenium‐catalyzed double hydrosilylation of alkynes with dihydrooligosilanes. The structural and photophysical features of the bis(alkenyl)oligosilanes were studied by X‐ray crystallography and UV and fluorescence spectra. The functional groups on the alkenyl moieties significantly affect not only their conformation and arrangement in crystals but also the UV and fluorescence spectra.
doi_str_mv 10.1002/ajoc.202400567
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title Synthesis of Bis(alkenyl)oligosilanes via Double Hydrosilylation and Their Structures and Photophysical Properties
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