Solvation thermodynamics of gas solubility at sub- and near-critical conditions

The recently developed formalism for describing the solute‐induced effect in dilute near‐critical mixtures is extended to fluids composed of anisotropic molecules through the statistical mechanical interpretation of the derivative (∂P/∂x2) T,p∞ whose critical value is the Krichevskii parameter. Rigo...

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Veröffentlicht in:	AIChE Journal 1996-02, Vol.42 (2), p.571-584
Hauptverfasser:	Chialvo, Ariel A., Kalyuzhnyi, Yu V., Cummings, Peter T.
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY DISSOLUTION GASES MATHEMATICAL MODELS MIXTURES SOLUTES SOLVATION THERMODYNAMIC PROPERTIES
Online-Zugang:	Volltext
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