Visible‐Light‐Driven Copper‐Catalyzed Synthesis of Sulfonamides from Aryl‐N 2 BF 4 through One‐pot Tricomponent Reaction
A method for preparing sulfonamides using visible light is described. In this approach, an aryl diazo tetrafluoroborate salt, 1,4‐diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO), and amino benzoate as substrates, CuBr 2 as a catalyst, and 3‐methyl‐3‐pentanol as an additive were employed for a...
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| Veröffentlicht in: | Advanced synthesis & catalysis 2023-05, Vol.365 (10), p.1671-1677 |
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| container_title | Advanced synthesis & catalysis |
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| creator | Giang Luu, Truong Kim, Hee‐Kwon |
| description | A method for preparing sulfonamides using visible light is described. In this approach, an aryl diazo tetrafluoroborate salt, 1,4‐diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO), and amino benzoate as substrates, CuBr
2
as a catalyst, and 3‐methyl‐3‐pentanol as an additive were employed for a one‐pot multicomponent reaction to provide sulfonamides under mild reaction conditions. A variety of aryl diazo tetrafluoroborate salts and
O
‐benzoyl hydroxylamines were tolerated in this process to provide products with yields up to 96%.
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| doi_str_mv | 10.1002/adsc.202300197 |
| format | Article |
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2
as a catalyst, and 3‐methyl‐3‐pentanol as an additive were employed for a one‐pot multicomponent reaction to provide sulfonamides under mild reaction conditions. A variety of aryl diazo tetrafluoroborate salts and
O
‐benzoyl hydroxylamines were tolerated in this process to provide products with yields up to 96%.
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2
as a catalyst, and 3‐methyl‐3‐pentanol as an additive were employed for a one‐pot multicomponent reaction to provide sulfonamides under mild reaction conditions. A variety of aryl diazo tetrafluoroborate salts and
O
‐benzoyl hydroxylamines were tolerated in this process to provide products with yields up to 96%.
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2
as a catalyst, and 3‐methyl‐3‐pentanol as an additive were employed for a one‐pot multicomponent reaction to provide sulfonamides under mild reaction conditions. A variety of aryl diazo tetrafluoroborate salts and
O
‐benzoyl hydroxylamines were tolerated in this process to provide products with yields up to 96%.
magnified image</abstract><doi>10.1002/adsc.202300197</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-7612-7049</orcidid></addata></record> |
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| ispartof | Advanced synthesis & catalysis, 2023-05, Vol.365 (10), p.1671-1677 |
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| source | Wiley Journals |
| title | Visible‐Light‐Driven Copper‐Catalyzed Synthesis of Sulfonamides from Aryl‐N 2 BF 4 through One‐pot Tricomponent Reaction |
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