Synthesis of 2‐Alkenyl‐4 H ‐3,1‐Benzoxazin‐4‐Ones through HFIP‐Mediated Decarboxylative [4+2]‐Annulation of Isatoic Anhydrides with Cyclopropenones under Silver Catalysis

Synthesis of 2‐Alkenyl‐4 H ‐3,1‐Benzoxazin‐4‐Ones through HFIP‐Mediated Decarboxylative [4+2]‐Annulation of Isatoic Anhydrides with Cyclopropenones under Silver Catalysis

We herein describes an HFIP‐mediated [4+2]‐cycloaddition reaction from simple and easily available isatoic anhydrides and cyclopropenones under silver catalysis. This transformation involves the tandem decarboxylative esterification, intermolecular addition, intramolecular substitution, small ring o...

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Veröffentlicht in:Advanced synthesis & catalysis 2021-08, Vol.363 (16), p.4085-4090
Hauptverfasser: Yang, Mengqi, Wang, Jixin, Lv, Weiwei, Ba, Dan, Cheng, Guolin, Wang, Lianhui
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container_issue 16
container_start_page 4085
container_title Advanced synthesis & catalysis
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creator Yang, Mengqi
Wang, Jixin
Lv, Weiwei
Ba, Dan
Cheng, Guolin
Wang, Lianhui
description We herein describes an HFIP‐mediated [4+2]‐cycloaddition reaction from simple and easily available isatoic anhydrides and cyclopropenones under silver catalysis. This transformation involves the tandem decarboxylative esterification, intermolecular addition, intramolecular substitution, small ring opening and isomerization processes, which allows the rapid assembly of versatile 2‐diarylalkenyl‐4 H ‐3,1‐benzoxazin‐4‐ones. magnified image
doi_str_mv 10.1002/adsc.202100489
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title Synthesis of 2‐Alkenyl‐4 H ‐3,1‐Benzoxazin‐4‐Ones through HFIP‐Mediated Decarboxylative [4+2]‐Annulation of Isatoic Anhydrides with Cyclopropenones under Silver Catalysis
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