Regioselective Iron‐Catalysed Cross‐Coupling Reaction of Aryl Propargylic Bromides and Aryl Grignard Reagents

An iron‐catalysed Kumada‐type cross‐coupling reaction between aryl substituted propargylic bromides and arylmagnesium reagents has been developed. Propargylic coupling products were the main or only outcome, and propargyl/allene regioselectivity was shown to depend on the electronic nature of the su...

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Veröffentlicht in:Advanced synthesis & catalysis 2020-01, Vol.362 (1), p.146-151
Hauptverfasser: Manjon-Mata, Ines, Quiros, M. Teresa, Bunuel, Elena, Cardenas, Diego J.
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Sprache:eng
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