[OSSO]‐Type Fe(III) Metallate as Single‐Component Catalyst for the CO 2 Cycloaddition to Epoxides

[OSSO]‐Type Fe(III) Metallate as Single‐Component Catalyst for the CO 2 Cycloaddition to Epoxides

A new [OSSO]‐Fe(III) metallate complex was prepared and characterized. We demonstrated that such metallate is the real catalytic active species for the cycloaddition of CO 2 to the epoxides, formed from the in situ reaction of the related [OSSO]‐Fe(III) neutral complexes and tetrabutylammonium bromi...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Advanced synthesis & catalysis 2019-01, Vol.361 (2), p.283-288
Hauptverfasser: Della Monica, Francesco, Buonerba, Antonio, Paradiso, Veronica, Milione, Stefano, Grassi, Alfonso, Capacchione, Carmine
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 288
container_issue 2
container_start_page 283
container_title Advanced synthesis & catalysis
container_volume 361
creator Della Monica, Francesco
Buonerba, Antonio
Paradiso, Veronica
Milione, Stefano
Grassi, Alfonso
Capacchione, Carmine
description A new [OSSO]‐Fe(III) metallate complex was prepared and characterized. We demonstrated that such metallate is the real catalytic active species for the cycloaddition of CO 2 to the epoxides, formed from the in situ reaction of the related [OSSO]‐Fe(III) neutral complexes and tetrabutylammonium bromide. The metallate complex was used as a single component catalyst for the formation of cyclic organic carbonates from ten epoxides and CO 2 at 1 bar pressure with good activity. magnified image
doi_str_mv 10.1002/adsc.201801240
format Article
fullrecord <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1002_adsc_201801240</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1002_adsc_201801240</sourcerecordid><originalsourceid>FETCH-LOGICAL-c840-22d83e6fe03e0e4d13a9741f7d979ba6184096ae0fa1c49e7cdb4633dda229473</originalsourceid><addsrcrecordid>eNo9kL1OwzAUhS0EEqWwMnuEIeH6p3E8oqgtkYoytBtCkRvfQFAaR7EHsvEIPCNPQipQp3Ok8-kMHyG3DGIGwB-M9VXMgaXAuIQzMmMJW0SSJfr81BdwSa68_wBgKlVqRvCl2G6L15-v793YI13hXZ7n9_QZg2lbE5AaT7dN99bihGTu0LsOu0AzM-2jD7R2Aw3vSLOCcpqNVeuMtU1oXEeDo8vefTYW_TW5qE3r8eY_52S3Wu6yp2hTrPPscRNVqYSIc5sKTGoEgYDSMmG0kqxWViu9NwmbIJ0YhNqwSmpUld3LRAhrDedaKjEn8d9tNTjvB6zLfmgOZhhLBuXRUXl0VJ4ciV81aVts</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>[OSSO]‐Type Fe(III) Metallate as Single‐Component Catalyst for the CO 2 Cycloaddition to Epoxides</title><source>Access via Wiley Online Library</source><creator>Della Monica, Francesco ; Buonerba, Antonio ; Paradiso, Veronica ; Milione, Stefano ; Grassi, Alfonso ; Capacchione, Carmine</creator><creatorcontrib>Della Monica, Francesco ; Buonerba, Antonio ; Paradiso, Veronica ; Milione, Stefano ; Grassi, Alfonso ; Capacchione, Carmine</creatorcontrib><description>A new [OSSO]‐Fe(III) metallate complex was prepared and characterized. We demonstrated that such metallate is the real catalytic active species for the cycloaddition of CO 2 to the epoxides, formed from the in situ reaction of the related [OSSO]‐Fe(III) neutral complexes and tetrabutylammonium bromide. The metallate complex was used as a single component catalyst for the formation of cyclic organic carbonates from ten epoxides and CO 2 at 1 bar pressure with good activity. magnified image</description><identifier>ISSN: 1615-4150</identifier><identifier>EISSN: 1615-4169</identifier><identifier>DOI: 10.1002/adsc.201801240</identifier><language>eng</language><ispartof>Advanced synthesis &amp; catalysis, 2019-01, Vol.361 (2), p.283-288</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c840-22d83e6fe03e0e4d13a9741f7d979ba6184096ae0fa1c49e7cdb4633dda229473</citedby><cites>FETCH-LOGICAL-c840-22d83e6fe03e0e4d13a9741f7d979ba6184096ae0fa1c49e7cdb4633dda229473</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930</link.rule.ids></links><search><creatorcontrib>Della Monica, Francesco</creatorcontrib><creatorcontrib>Buonerba, Antonio</creatorcontrib><creatorcontrib>Paradiso, Veronica</creatorcontrib><creatorcontrib>Milione, Stefano</creatorcontrib><creatorcontrib>Grassi, Alfonso</creatorcontrib><creatorcontrib>Capacchione, Carmine</creatorcontrib><title>[OSSO]‐Type Fe(III) Metallate as Single‐Component Catalyst for the CO 2 Cycloaddition to Epoxides</title><title>Advanced synthesis &amp; catalysis</title><description>A new [OSSO]‐Fe(III) metallate complex was prepared and characterized. We demonstrated that such metallate is the real catalytic active species for the cycloaddition of CO 2 to the epoxides, formed from the in situ reaction of the related [OSSO]‐Fe(III) neutral complexes and tetrabutylammonium bromide. The metallate complex was used as a single component catalyst for the formation of cyclic organic carbonates from ten epoxides and CO 2 at 1 bar pressure with good activity. magnified image</description><issn>1615-4150</issn><issn>1615-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNo9kL1OwzAUhS0EEqWwMnuEIeH6p3E8oqgtkYoytBtCkRvfQFAaR7EHsvEIPCNPQipQp3Ok8-kMHyG3DGIGwB-M9VXMgaXAuIQzMmMJW0SSJfr81BdwSa68_wBgKlVqRvCl2G6L15-v793YI13hXZ7n9_QZg2lbE5AaT7dN99bihGTu0LsOu0AzM-2jD7R2Aw3vSLOCcpqNVeuMtU1oXEeDo8vefTYW_TW5qE3r8eY_52S3Wu6yp2hTrPPscRNVqYSIc5sKTGoEgYDSMmG0kqxWViu9NwmbIJ0YhNqwSmpUld3LRAhrDedaKjEn8d9tNTjvB6zLfmgOZhhLBuXRUXl0VJ4ciV81aVts</recordid><startdate>20190122</startdate><enddate>20190122</enddate><creator>Della Monica, Francesco</creator><creator>Buonerba, Antonio</creator><creator>Paradiso, Veronica</creator><creator>Milione, Stefano</creator><creator>Grassi, Alfonso</creator><creator>Capacchione, Carmine</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20190122</creationdate><title>[OSSO]‐Type Fe(III) Metallate as Single‐Component Catalyst for the CO 2 Cycloaddition to Epoxides</title><author>Della Monica, Francesco ; Buonerba, Antonio ; Paradiso, Veronica ; Milione, Stefano ; Grassi, Alfonso ; Capacchione, Carmine</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c840-22d83e6fe03e0e4d13a9741f7d979ba6184096ae0fa1c49e7cdb4633dda229473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Della Monica, Francesco</creatorcontrib><creatorcontrib>Buonerba, Antonio</creatorcontrib><creatorcontrib>Paradiso, Veronica</creatorcontrib><creatorcontrib>Milione, Stefano</creatorcontrib><creatorcontrib>Grassi, Alfonso</creatorcontrib><creatorcontrib>Capacchione, Carmine</creatorcontrib><collection>CrossRef</collection><jtitle>Advanced synthesis &amp; catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Della Monica, Francesco</au><au>Buonerba, Antonio</au><au>Paradiso, Veronica</au><au>Milione, Stefano</au><au>Grassi, Alfonso</au><au>Capacchione, Carmine</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>[OSSO]‐Type Fe(III) Metallate as Single‐Component Catalyst for the CO 2 Cycloaddition to Epoxides</atitle><jtitle>Advanced synthesis &amp; catalysis</jtitle><date>2019-01-22</date><risdate>2019</risdate><volume>361</volume><issue>2</issue><spage>283</spage><epage>288</epage><pages>283-288</pages><issn>1615-4150</issn><eissn>1615-4169</eissn><abstract>A new [OSSO]‐Fe(III) metallate complex was prepared and characterized. We demonstrated that such metallate is the real catalytic active species for the cycloaddition of CO 2 to the epoxides, formed from the in situ reaction of the related [OSSO]‐Fe(III) neutral complexes and tetrabutylammonium bromide. The metallate complex was used as a single component catalyst for the formation of cyclic organic carbonates from ten epoxides and CO 2 at 1 bar pressure with good activity. magnified image</abstract><doi>10.1002/adsc.201801240</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1615-4150
ispartof Advanced synthesis & catalysis, 2019-01, Vol.361 (2), p.283-288
issn 1615-4150
1615-4169
language eng
recordid cdi_crossref_primary_10_1002_adsc_201801240
source Access via Wiley Online Library
title [OSSO]‐Type Fe(III) Metallate as Single‐Component Catalyst for the CO 2 Cycloaddition to Epoxides
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-16T06%3A31%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=%5BOSSO%5D%E2%80%90Type%20Fe(III)%20Metallate%20as%20Single%E2%80%90Component%20Catalyst%20for%20the%20CO%202%20Cycloaddition%20to%20Epoxides&rft.jtitle=Advanced%20synthesis%20&%20catalysis&rft.au=Della%E2%80%85Monica,%20Francesco&rft.date=2019-01-22&rft.volume=361&rft.issue=2&rft.spage=283&rft.epage=288&rft.pages=283-288&rft.issn=1615-4150&rft.eissn=1615-4169&rft_id=info:doi/10.1002/adsc.201801240&rft_dat=%3Ccrossref%3E10_1002_adsc_201801240%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true