On the Mechanism of Asymmetric Epoxidation of Enones Catalyzed by α,α-L-Diarylprolinols: A Theoretical Insight

The mechanism of the asymmetric epoxidation of enones with tert‐butyl hydroperoxide promoted by α,α‐L‐diarylprolinols has been studied by second order Møller–Plesset perturbation theory (MP2) and density functional theory (DFT) computations. The non‐covalent activation of the reactants, through an e...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Advanced synthesis & catalysis 2012-10, Vol.354 (14-15), p.2789-2796
Hauptverfasser:	Capobianco, Amedeo, Russo, Alessio, Lattanzi, Alessandra, Peluso, Andrea
Format:	Artikel
Sprache:	eng
Schlagworte:	asymmetric epoxidation Catalysis Catalysts: preparations and properties Chemistry density functional calculations enones Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Heterocyclic compounds with only one n hetero atom and condensed derivatives Kinetics and mechanisms mechanism Organic chemistry organocatalysis Preparations and properties Reactivity and mechanisms Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!