Asymmetric Intramolecular CH Insertion of α-Diazoacetamides in Water by Dirhodium(II) Catalysts Derived from Natural Amino Acids

The asymmetric dirhodium(II)‐catalyzed intramolecular CH insertion of α‐diazo acetamides in water is described for the first time. The use of natural α‐amino acids as chiral ligands allowed the preparation of novel dirhodium(II) homochiral complexes by a simple procedure consisting of the in situ l...

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Veröffentlicht in:	Advanced synthesis & catalysis 2012-11, Vol.354 (16), p.2921-2927
Hauptverfasser:	Candeias, Nuno R., Carias, Carolina, Gomes, Luis F. R., André, Vânia, Duarte, M. Teresa, Gois, Pedro M. P., Afonso, Carlos A. M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts: preparations and properties Chemistry CH insertion dirhodium(II) Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Organic chemistry Preparations and properties Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry water α-diazo compounds β-lactams
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