Iron‐Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P 2 N 4 ‐Type Macrocycles

Novel P 2 N 4 ‐donors containing chiral 22‐membered macrocyclic ligands have been synthesized and the structures have been determined by an X‐ray diffraction study. The catalytic systems in situ generated from triiron dodecarbonyl, Fe 3 (CO) 12 , and the chiral macrocyclic ligand exhibited high acti...

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Veröffentlicht in:Advanced synthesis & catalysis 2012-03, Vol.354 (5), p.818-822
Hauptverfasser: Yu, Shenluan, Shen, Weiyi, Li, Yanyun, Dong, Zhenrong, Xu, Yaqing, Li, Qi, Zhang, Juanni, Gao, Jingxing
Format: Artikel
Sprache:eng
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