Iron‐Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P 2 N 4 ‐Type Macrocycles
Novel P 2 N 4 ‐donors containing chiral 22‐membered macrocyclic ligands have been synthesized and the structures have been determined by an X‐ray diffraction study. The catalytic systems in situ generated from triiron dodecarbonyl, Fe 3 (CO) 12 , and the chiral macrocyclic ligand exhibited high acti...
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| Veröffentlicht in: | Advanced synthesis & catalysis 2012-03, Vol.354 (5), p.818-822 |
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| container_end_page | 822 |
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| container_issue | 5 |
| container_start_page | 818 |
| container_title | Advanced synthesis & catalysis |
| container_volume | 354 |
| creator | Yu, Shenluan Shen, Weiyi Li, Yanyun Dong, Zhenrong Xu, Yaqing Li, Qi Zhang, Juanni Gao, Jingxing |
| description | Novel P
2
N
4
‐donors containing chiral 22‐membered macrocyclic ligands have been synthesized and the structures have been determined by an X‐ray diffraction study. The catalytic systems
in situ
generated from triiron dodecarbonyl, Fe
3
(CO)
12
, and the chiral macrocyclic ligand exhibited high activity (TOF up to 1940 h
−1
) and excellent enantioselectivity with up to 99%
ee
in the asymmetric transfer hydrogenation of various aromatic ketones. |
| doi_str_mv | 10.1002/adsc.201100733 |
| format | Article |
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2
N
4
‐donors containing chiral 22‐membered macrocyclic ligands have been synthesized and the structures have been determined by an X‐ray diffraction study. The catalytic systems
in situ
generated from triiron dodecarbonyl, Fe
3
(CO)
12
, and the chiral macrocyclic ligand exhibited high activity (TOF up to 1940 h
−1
) and excellent enantioselectivity with up to 99%
ee
in the asymmetric transfer hydrogenation of various aromatic ketones.</description><identifier>ISSN: 1615-4150</identifier><identifier>EISSN: 1615-4169</identifier><identifier>DOI: 10.1002/adsc.201100733</identifier><language>eng</language><ispartof>Advanced synthesis & catalysis, 2012-03, Vol.354 (5), p.818-822</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c843-3f23a43b6350a9d3248f75c0ad9692416119a36870bb49a35c4bd2a8c132663d3</citedby><cites>FETCH-LOGICAL-c843-3f23a43b6350a9d3248f75c0ad9692416119a36870bb49a35c4bd2a8c132663d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Yu, Shenluan</creatorcontrib><creatorcontrib>Shen, Weiyi</creatorcontrib><creatorcontrib>Li, Yanyun</creatorcontrib><creatorcontrib>Dong, Zhenrong</creatorcontrib><creatorcontrib>Xu, Yaqing</creatorcontrib><creatorcontrib>Li, Qi</creatorcontrib><creatorcontrib>Zhang, Juanni</creatorcontrib><creatorcontrib>Gao, Jingxing</creatorcontrib><title>Iron‐Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P 2 N 4 ‐Type Macrocycles</title><title>Advanced synthesis & catalysis</title><description>Novel P
2
N
4
‐donors containing chiral 22‐membered macrocyclic ligands have been synthesized and the structures have been determined by an X‐ray diffraction study. The catalytic systems
in situ
generated from triiron dodecarbonyl, Fe
3
(CO)
12
, and the chiral macrocyclic ligand exhibited high activity (TOF up to 1940 h
−1
) and excellent enantioselectivity with up to 99%
ee
in the asymmetric transfer hydrogenation of various aromatic ketones.</description><issn>1615-4150</issn><issn>1615-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNo9kMtOwzAQRS0EEqWwZT0_kOJXnGRZRYVWlIdQ99HEdqhRGld2AIUVn8A38iUEgbqaM5t7dQ8hl4zOGKX8Ck3UM07Z-GRCHJEJUyxNJFPF8YFTekrOYnyhlGV5lk1Itwq--_78KrHHdviwBpbuedsOsOiw652PtrW6d28Wnqx5Hcl34BuYB7_D3mm4tb3vbIR312-h3LqALTwCh3uQMMZuhr2FO9TB60G3Np6TkwbbaC_-75RsrhebcpmsH25W5Xyd6FyKRDRcoBS1EinFwggu8yZLNUVTqIKPixgrUKg8o3UtR0q1rA3HXDPBlRJGTMnsL3YsjjHYptoHt8MwVIxWv7KqX1nVQZb4AZ5OXqQ</recordid><startdate>20120316</startdate><enddate>20120316</enddate><creator>Yu, Shenluan</creator><creator>Shen, Weiyi</creator><creator>Li, Yanyun</creator><creator>Dong, Zhenrong</creator><creator>Xu, Yaqing</creator><creator>Li, Qi</creator><creator>Zhang, Juanni</creator><creator>Gao, Jingxing</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20120316</creationdate><title>Iron‐Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P 2 N 4 ‐Type Macrocycles</title><author>Yu, Shenluan ; Shen, Weiyi ; Li, Yanyun ; Dong, Zhenrong ; Xu, Yaqing ; Li, Qi ; Zhang, Juanni ; Gao, Jingxing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c843-3f23a43b6350a9d3248f75c0ad9692416119a36870bb49a35c4bd2a8c132663d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yu, Shenluan</creatorcontrib><creatorcontrib>Shen, Weiyi</creatorcontrib><creatorcontrib>Li, Yanyun</creatorcontrib><creatorcontrib>Dong, Zhenrong</creatorcontrib><creatorcontrib>Xu, Yaqing</creatorcontrib><creatorcontrib>Li, Qi</creatorcontrib><creatorcontrib>Zhang, Juanni</creatorcontrib><creatorcontrib>Gao, Jingxing</creatorcontrib><collection>CrossRef</collection><jtitle>Advanced synthesis & catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yu, Shenluan</au><au>Shen, Weiyi</au><au>Li, Yanyun</au><au>Dong, Zhenrong</au><au>Xu, Yaqing</au><au>Li, Qi</au><au>Zhang, Juanni</au><au>Gao, Jingxing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Iron‐Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P 2 N 4 ‐Type Macrocycles</atitle><jtitle>Advanced synthesis & catalysis</jtitle><date>2012-03-16</date><risdate>2012</risdate><volume>354</volume><issue>5</issue><spage>818</spage><epage>822</epage><pages>818-822</pages><issn>1615-4150</issn><eissn>1615-4169</eissn><abstract>Novel P
2
N
4
‐donors containing chiral 22‐membered macrocyclic ligands have been synthesized and the structures have been determined by an X‐ray diffraction study. The catalytic systems
in situ
generated from triiron dodecarbonyl, Fe
3
(CO)
12
, and the chiral macrocyclic ligand exhibited high activity (TOF up to 1940 h
−1
) and excellent enantioselectivity with up to 99%
ee
in the asymmetric transfer hydrogenation of various aromatic ketones.</abstract><doi>10.1002/adsc.201100733</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1615-4150 |
| ispartof | Advanced synthesis & catalysis, 2012-03, Vol.354 (5), p.818-822 |
| issn | 1615-4150 1615-4169 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_adsc_201100733 |
| source | Wiley Online Library - AutoHoldings Journals |
| title | Iron‐Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P 2 N 4 ‐Type Macrocycles |
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