Pyrazolate-Based Dinuclear α-Diimine-Type Palladium(II) and Nickel(II) Complexes - a Bimetallic Approach in Olefin Polymerisation

A series of compartmental pyrazole/imine dinucleating ligands HL1–HL4 have been prepared with different backbone substitutents and different steric bulk of the appending arylimine groups, and two of them have been structurally characterised. With PdCl2 all ligands form the anticipated pyrazolate‐bri...

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Veröffentlicht in:Advanced synthesis & catalysis 2006-05, Vol.348 (7-8), p.887-897
Hauptverfasser: Noël, Gilles, Röder, Jens C., Dechert, Sebastian, Pritzkow, Hans, Bolk, Lars, Mecking, Stefan, Meyer, Franc
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Sprache:eng
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