Biocatalytic Asymmetric Dihydroxylation of Conjugated Mono- and Poly-alkenes to Yield Enantiopure Cyclic cis-Diols

Dioxygenase‐catalysed asymmetric dihydroxylation, of a series of conjugated monoalkenes and polyenes, was found to yield the corresponding monols and 1,2‐dihydrodiols. The diol metabolites were obtained from monosubstituted, gem‐disubstituted, cis‐disubstituted, and trisubstituted alkene substrates,...

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Veröffentlicht in:	Advanced synthesis & catalysis 2005-06, Vol.347 (7-8), p.1081-1089
Hauptverfasser:	Boyd, Derek R., Sharma, Narain D., Bowers, Nigel I., Brannigan, Ian N., Groocock, Melanie R., Malone, John F., McConville, Gareth, Allen, Christopher C. R.
Format:	Artikel
Sprache:	eng
Schlagworte:	allylic/benzylic hydroxylation asymmetric alkene/arene dihydroxylation chemoenzymatic synthesis dioxygenases
Online-Zugang:	Volltext
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