Ruthenium(III) Chloride-Catalyzed Thioacetalization of Carbonyl Compounds: Scope, Selectivity, and Limitations
A variety of carbonyl compounds can be easily and rapidly converted to the corresponding cyclic and acylic dithioacetals in the presence of a catalytic amount of ruthenium chloride in acetonitrile at room temperature. Some of the major advantages of this protocol are high chemoselectivity, operation...
Gespeichert in:
| Veröffentlicht in: | Advanced synthesis & catalysis 2005-04, Vol.347 (5), p.673-676 |
|---|---|
| 1. Verfasser: | |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 676 |
|---|---|
| container_issue | 5 |
| container_start_page | 673 |
| container_title | Advanced synthesis & catalysis |
| container_volume | 347 |
| creator | De, Surya Kanta |
| description | A variety of carbonyl compounds can be easily and rapidly converted to the corresponding cyclic and acylic dithioacetals in the presence of a catalytic amount of ruthenium chloride in acetonitrile at room temperature. Some of the major advantages of this protocol are high chemoselectivity, operational simplicity, very short reaction times, high yields, and also compatibility with other protecting groups. |
| doi_str_mv | 10.1002/adsc.200404323 |
| format | Article |
| fullrecord | <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_adsc_200404323</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_WNG_LNRNZ119_C</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3273-c617fa47d72213062901d082e6bc0efb4b755f2748b1fb86449eceb39442db373</originalsourceid><addsrcrecordid>eNqF0M9LwzAUB_AgCs7p1XOOCuvMrzattxF1FsqEbSJ4CWmasmjXjKZTu7_ezcnw5um9B9_PO3wBuMRoiBEiN6rwekgQYohRQo9AD0c4DBiOkuPDHqJTcOb9G0KYx5z3QD1dtwtT2_XyKk3TaygWlWtsYQKhWlV1G1PA-cI6pc32tBvVWldDV0KhmtzVXQWFW67cui78LZxptzIDODOV0a39sG03gKouYGaXtv2R_hyclKry5uJ39sHzw_1cPAbZ0zgVoyzQlHAa6AjzUjFecEIwRRFJEC5QTEyUa2TKnOU8DEvCWZzjMo8jxhKjTU4TxkiRU077YLj_qxvnfWNKuWrsUjWdxEju2pK7tuShrS1I9uDTVqb7Jy1HdzPx1wZ7a31rvg5WNe8y4pSH8mUyltlkOnnFOJGCfgPBH35-</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Ruthenium(III) Chloride-Catalyzed Thioacetalization of Carbonyl Compounds: Scope, Selectivity, and Limitations</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>De, Surya Kanta</creator><creatorcontrib>De, Surya Kanta</creatorcontrib><description>A variety of carbonyl compounds can be easily and rapidly converted to the corresponding cyclic and acylic dithioacetals in the presence of a catalytic amount of ruthenium chloride in acetonitrile at room temperature. Some of the major advantages of this protocol are high chemoselectivity, operational simplicity, very short reaction times, high yields, and also compatibility with other protecting groups.</description><identifier>ISSN: 1615-4150</identifier><identifier>EISSN: 1615-4169</identifier><identifier>DOI: 10.1002/adsc.200404323</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>aldehydes ; chemoselectivity ; dithioacetals ; ketones ; protecting groups ; ruthenium chloride</subject><ispartof>Advanced synthesis & catalysis, 2005-04, Vol.347 (5), p.673-676</ispartof><rights>Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3273-c617fa47d72213062901d082e6bc0efb4b755f2748b1fb86449eceb39442db373</citedby><cites>FETCH-LOGICAL-c3273-c617fa47d72213062901d082e6bc0efb4b755f2748b1fb86449eceb39442db373</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadsc.200404323$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45551</link.rule.ids></links><search><creatorcontrib>De, Surya Kanta</creatorcontrib><title>Ruthenium(III) Chloride-Catalyzed Thioacetalization of Carbonyl Compounds: Scope, Selectivity, and Limitations</title><title>Advanced synthesis & catalysis</title><addtitle>Adv. Synth. Catal</addtitle><description>A variety of carbonyl compounds can be easily and rapidly converted to the corresponding cyclic and acylic dithioacetals in the presence of a catalytic amount of ruthenium chloride in acetonitrile at room temperature. Some of the major advantages of this protocol are high chemoselectivity, operational simplicity, very short reaction times, high yields, and also compatibility with other protecting groups.</description><subject>aldehydes</subject><subject>chemoselectivity</subject><subject>dithioacetals</subject><subject>ketones</subject><subject>protecting groups</subject><subject>ruthenium chloride</subject><issn>1615-4150</issn><issn>1615-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqF0M9LwzAUB_AgCs7p1XOOCuvMrzattxF1FsqEbSJ4CWmasmjXjKZTu7_ezcnw5um9B9_PO3wBuMRoiBEiN6rwekgQYohRQo9AD0c4DBiOkuPDHqJTcOb9G0KYx5z3QD1dtwtT2_XyKk3TaygWlWtsYQKhWlV1G1PA-cI6pc32tBvVWldDV0KhmtzVXQWFW67cui78LZxptzIDODOV0a39sG03gKouYGaXtv2R_hyclKry5uJ39sHzw_1cPAbZ0zgVoyzQlHAa6AjzUjFecEIwRRFJEC5QTEyUa2TKnOU8DEvCWZzjMo8jxhKjTU4TxkiRU077YLj_qxvnfWNKuWrsUjWdxEju2pK7tuShrS1I9uDTVqb7Jy1HdzPx1wZ7a31rvg5WNe8y4pSH8mUyltlkOnnFOJGCfgPBH35-</recordid><startdate>200504</startdate><enddate>200504</enddate><creator>De, Surya Kanta</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200504</creationdate><title>Ruthenium(III) Chloride-Catalyzed Thioacetalization of Carbonyl Compounds: Scope, Selectivity, and Limitations</title><author>De, Surya Kanta</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3273-c617fa47d72213062901d082e6bc0efb4b755f2748b1fb86449eceb39442db373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>aldehydes</topic><topic>chemoselectivity</topic><topic>dithioacetals</topic><topic>ketones</topic><topic>protecting groups</topic><topic>ruthenium chloride</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>De, Surya Kanta</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Advanced synthesis & catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>De, Surya Kanta</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ruthenium(III) Chloride-Catalyzed Thioacetalization of Carbonyl Compounds: Scope, Selectivity, and Limitations</atitle><jtitle>Advanced synthesis & catalysis</jtitle><addtitle>Adv. Synth. Catal</addtitle><date>2005-04</date><risdate>2005</risdate><volume>347</volume><issue>5</issue><spage>673</spage><epage>676</epage><pages>673-676</pages><issn>1615-4150</issn><eissn>1615-4169</eissn><abstract>A variety of carbonyl compounds can be easily and rapidly converted to the corresponding cyclic and acylic dithioacetals in the presence of a catalytic amount of ruthenium chloride in acetonitrile at room temperature. Some of the major advantages of this protocol are high chemoselectivity, operational simplicity, very short reaction times, high yields, and also compatibility with other protecting groups.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/adsc.200404323</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1615-4150 |
| ispartof | Advanced synthesis & catalysis, 2005-04, Vol.347 (5), p.673-676 |
| issn | 1615-4150 1615-4169 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_adsc_200404323 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | aldehydes chemoselectivity dithioacetals ketones protecting groups ruthenium chloride |
| title | Ruthenium(III) Chloride-Catalyzed Thioacetalization of Carbonyl Compounds: Scope, Selectivity, and Limitations |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-09T08%3A18%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ruthenium(III)%20Chloride-Catalyzed%20Thioacetalization%20of%20Carbonyl%20Compounds:%20Scope,%20Selectivity,%20and%20Limitations&rft.jtitle=Advanced%20synthesis%20&%20catalysis&rft.au=De,%20Surya%E2%80%85Kanta&rft.date=2005-04&rft.volume=347&rft.issue=5&rft.spage=673&rft.epage=676&rft.pages=673-676&rft.issn=1615-4150&rft.eissn=1615-4169&rft_id=info:doi/10.1002/adsc.200404323&rft_dat=%3Cistex_cross%3Eark_67375_WNG_LNRNZ119_C%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |