A Rapid and Efficient Synthesis of Quinone Derivatives: Ru(II)- or Ir(I)-Catalyzed Hydrogen Peroxide Oxidation of Phenols and Methoxyarenes

A Rapid and Efficient Synthesis of Quinone Derivatives: Ru(II)- or Ir(I)-Catalyzed Hydrogen Peroxide Oxidation of Phenols and Methoxyarenes

Hydroquinone and methoxybenzene derivatives were catalytically oxidized promptly to the corresponding quinones in up to 99% yield. With a catalyst loading of 0.01 mol %, a maximum TON of 8.4×103 was attained in the case of Ru(II)‐complex. Ru(II)(pybox‐dh)(pydic) is able to enhance the hydrogen perox...

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Veröffentlicht in:Advanced synthesis & catalysis 2005-03, Vol.347 (4), p.517-520
Hauptverfasser: Iwasa, Seiji, Fakhruddin, Ahmad, Widagdo, Herman Setyo, Nishiyama, Hisao
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Sprache:eng
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homogeneous catalysis
hydrogen peroxide
hydroquinones
N ligands
oxidation
ruthenium
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container_issue 4
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container_title Advanced synthesis & catalysis
container_volume 347
creator Iwasa, Seiji
Fakhruddin, Ahmad
Widagdo, Herman Setyo
Nishiyama, Hisao
description Hydroquinone and methoxybenzene derivatives were catalytically oxidized promptly to the corresponding quinones in up to 99% yield. With a catalyst loading of 0.01 mol %, a maximum TON of 8.4×103 was attained in the case of Ru(II)‐complex. Ru(II)(pybox‐dh)(pydic) is able to enhance the hydrogen peroxide oxidation of substituted hydroquinones as well as methoxybenzenes, but Ir[(coe)2Cl]2 and Ir[(cod)Cl]2 were found to be effective catalysts only for the former substrates under similar oxidation conditions.
doi_str_mv 10.1002/adsc.200404287
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subjects homogeneous catalysis
hydrogen peroxide
hydroquinones
N ligands
oxidation
ruthenium
title A Rapid and Efficient Synthesis of Quinone Derivatives: Ru(II)- or Ir(I)-Catalyzed Hydrogen Peroxide Oxidation of Phenols and Methoxyarenes
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