Rhodium-Catalyzed Hydrogenation of Alkenes by Rhodium/Tris(fluoroalkoxy)phosphane Complexes in Fluorous Biphasic System

The reaction of [Ir(μ‐Cl)(COD)]2 with various fluorous derivatives of triphenylphosphane containing a para‐, meta‐, or ortho‐(1H,1H‐perfluoroalkoxy)‐substituted fluorous phosphane P(C6H4‐ORf)3 (Rf=CH2C7F15, CH2CH2CH2C8F17) and CO (1 atm) gives the corresponding trans‐[Ir(μ‐Cl)(CO){P(C6H4ORf)3}2]. Th...

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Veröffentlicht in:	Advanced synthesis & catalysis 2003-05, Vol.345 (5), p.603-611
Hauptverfasser:	Sinou, Denis, Maillard, David, Aghmiz, Ali, Masdeu i-Bultó, Anna M.
Format:	Artikel
Sprache:	eng
Schlagworte:	biphasic catalysis catalyst recycling fluorous hydrogenation iridium rhodium
Online-Zugang:	Volltext
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