Nanopore/Nanosphere‐Induced Optical Enhancement of Monolayer MoS 2

Heterostructured transition metal dichalcogenides (TMDs) have received much attention due to their tunable optical and electronic properties. Here, a strategy for facile fabrication of porous anodic alumina (PAA) membrane‐supported monolayer molybdenum disulfide (MoS 2 ) is described. PAA is either...

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Veröffentlicht in:Advanced optical materials 2023-08, Vol.11 (16)
Hauptverfasser: Li, Yueqi, Chen, Zhexue, Zhou, Xuanping, Wu, Xianxin, Zhou, Zhican, Li, Zhangqiang, Xiao, Liuyang, Liu, Qian, Liu, Xinfeng, Zhang, Yong
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container_issue 16
container_start_page
container_title Advanced optical materials
container_volume 11
creator Li, Yueqi
Chen, Zhexue
Zhou, Xuanping
Wu, Xianxin
Zhou, Zhican
Li, Zhangqiang
Xiao, Liuyang
Liu, Qian
Liu, Xinfeng
Zhang, Yong
description Heterostructured transition metal dichalcogenides (TMDs) have received much attention due to their tunable optical and electronic properties. Here, a strategy for facile fabrication of porous anodic alumina (PAA) membrane‐supported monolayer molybdenum disulfide (MoS 2 ) is described. PAA is either empty or filled with gold nanoparticles (AuNPs). Such nanopore/nanosphere‐supported MoS 2 (i.e., PAA‐MoS 2 and PAA‐Au‐MoS 2 ) exhibits greatly enhanced optical performances compared with those of silicon wafer‐supported MoS 2 (i.e., Si/SiO 2 ‐MoS 2 ). Notably, 11‐fold Raman enhancement, 13‐fold photoluminescence enhancement, and 419‐fold second‐harmonic generation enhancement are achieved in PAA‐Au‐MoS 2 . Moreover, the optical enhancement mechanism of this unique structure is proposed. This work provides a platform for the construction of curved/heterostructured TMDs and exploration of their strong light‐matter interactions.
doi_str_mv 10.1002/adom.202300120
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Here, a strategy for facile fabrication of porous anodic alumina (PAA) membrane‐supported monolayer molybdenum disulfide (MoS 2 ) is described. PAA is either empty or filled with gold nanoparticles (AuNPs). Such nanopore/nanosphere‐supported MoS 2 (i.e., PAA‐MoS 2 and PAA‐Au‐MoS 2 ) exhibits greatly enhanced optical performances compared with those of silicon wafer‐supported MoS 2 (i.e., Si/SiO 2 ‐MoS 2 ). Notably, 11‐fold Raman enhancement, 13‐fold photoluminescence enhancement, and 419‐fold second‐harmonic generation enhancement are achieved in PAA‐Au‐MoS 2 . Moreover, the optical enhancement mechanism of this unique structure is proposed. 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