Surface-Energy-Regulated Growth of α-Phase Cs 0.03 FA 0.97 PbI 3 for Highly Efficient and Stable Inverted Perovskite Solar Cells
Methylammonium (MA)-free formamidinium (FA)-dominated Cs FA PbI is rising as the most promising candidate for highly efficient and stable perovskite solar cells. However, the growth of high-quality Cs FA PbI black-phase perovskite structure without ion doping in the lattice remains a challenge. Here...
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| Veröffentlicht in: | Advanced materials (Weinheim) 2023-04, Vol.35 (15), p.e2208522 |
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| container_title | Advanced materials (Weinheim) |
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| creator | Pan, Ting Zhou, Wei Wei, Qi Peng, Zijian Wang, Hao Jiang, Xianyuan Zang, Zihao Li, Hansheng Yu, Danni Zhou, Qilin Pan, Mengling Zhou, Wenjia Ning, Zhijun |
| description | Methylammonium (MA)-free formamidinium (FA)-dominated Cs
FA
PbI
is rising as the most promising candidate for highly efficient and stable perovskite solar cells. However, the growth of high-quality Cs
FA
PbI
black-phase perovskite structure without ion doping in the lattice remains a challenge. Herein, propeller-shaped halogenated tertiary ammonium is synthesized, showing high binding energy on the perovskite surface and large steric hindrance. This molecule can significantly reduce the barrier of high surface energy that suppresses the growth of the α-phase Cs
FA
PbI
structure. As a result, the α-phase structure can be formed at room temperature, which can further act as a seed for the growth of high-quality film. Solar cells based on the film show a record efficiency up to 23.6% for MA free Cs
FA
PbI
solar cells with inverted structure and excellent stability at 85 °C over 200 h. |
| doi_str_mv | 10.1002/adma.202208522 |
| format | Article |
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FA
PbI
is rising as the most promising candidate for highly efficient and stable perovskite solar cells. However, the growth of high-quality Cs
FA
PbI
black-phase perovskite structure without ion doping in the lattice remains a challenge. Herein, propeller-shaped halogenated tertiary ammonium is synthesized, showing high binding energy on the perovskite surface and large steric hindrance. This molecule can significantly reduce the barrier of high surface energy that suppresses the growth of the α-phase Cs
FA
PbI
structure. As a result, the α-phase structure can be formed at room temperature, which can further act as a seed for the growth of high-quality film. Solar cells based on the film show a record efficiency up to 23.6% for MA free Cs
FA
PbI
solar cells with inverted structure and excellent stability at 85 °C over 200 h.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.202208522</identifier><identifier>PMID: 36692303</identifier><language>eng</language><publisher>Germany</publisher><ispartof>Advanced materials (Weinheim), 2023-04, Vol.35 (15), p.e2208522</ispartof><rights>2023 Wiley-VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1073-52614dda965fb2592eeb41d33096d9ae6f5079bcf79eb5f612492ccf0db15cda3</citedby><cites>FETCH-LOGICAL-c1073-52614dda965fb2592eeb41d33096d9ae6f5079bcf79eb5f612492ccf0db15cda3</cites><orcidid>0000-0002-9130-3490</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27911,27912</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36692303$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Pan, Ting</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Wei, Qi</creatorcontrib><creatorcontrib>Peng, Zijian</creatorcontrib><creatorcontrib>Wang, Hao</creatorcontrib><creatorcontrib>Jiang, Xianyuan</creatorcontrib><creatorcontrib>Zang, Zihao</creatorcontrib><creatorcontrib>Li, Hansheng</creatorcontrib><creatorcontrib>Yu, Danni</creatorcontrib><creatorcontrib>Zhou, Qilin</creatorcontrib><creatorcontrib>Pan, Mengling</creatorcontrib><creatorcontrib>Zhou, Wenjia</creatorcontrib><creatorcontrib>Ning, Zhijun</creatorcontrib><title>Surface-Energy-Regulated Growth of α-Phase Cs 0.03 FA 0.97 PbI 3 for Highly Efficient and Stable Inverted Perovskite Solar Cells</title><title>Advanced materials (Weinheim)</title><addtitle>Adv Mater</addtitle><description>Methylammonium (MA)-free formamidinium (FA)-dominated Cs
FA
PbI
is rising as the most promising candidate for highly efficient and stable perovskite solar cells. However, the growth of high-quality Cs
FA
PbI
black-phase perovskite structure without ion doping in the lattice remains a challenge. Herein, propeller-shaped halogenated tertiary ammonium is synthesized, showing high binding energy on the perovskite surface and large steric hindrance. This molecule can significantly reduce the barrier of high surface energy that suppresses the growth of the α-phase Cs
FA
PbI
structure. As a result, the α-phase structure can be formed at room temperature, which can further act as a seed for the growth of high-quality film. Solar cells based on the film show a record efficiency up to 23.6% for MA free Cs
FA
PbI
solar cells with inverted structure and excellent stability at 85 °C over 200 h.</description><issn>0935-9648</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNo9kNFOwjAYhRujEURvvTR9gc2_7drRS0IQSEgkotdLt_6F6dhIOzBc-ki-iM8kBOXq3JzzJecj5J5BzAD4o7FrE3PgHPqS8wvSZZKzKAEtL0kXtJCRVkm_Q25CeAcArUBdk45QSnMBoku-FlvvTIHRqEa_3EcvuNxWpkVLx775bFe0cfTnO5qvTEA6DBRiEPRpcEid0nk-pYK6xtNJuVxVezpyrixKrFtqaksXrckrpNN6h_5InKNvduGjbJEumsp4OsSqCrfkypkq4N1f9sjb0-h1OIlmz-PpcDCLCgapiCRXLLHWaCVdzqXmiHnCrBCHT1YbVE5CqvPCpRpz6RTjieZF4cDmTBbWiB6JT9zCNyF4dNnGl2vj9xmD7OgyO7rMzi4Pg4fTYLPN12jP9X954hcxiW7t</recordid><startdate>202304</startdate><enddate>202304</enddate><creator>Pan, Ting</creator><creator>Zhou, Wei</creator><creator>Wei, Qi</creator><creator>Peng, Zijian</creator><creator>Wang, Hao</creator><creator>Jiang, Xianyuan</creator><creator>Zang, Zihao</creator><creator>Li, Hansheng</creator><creator>Yu, Danni</creator><creator>Zhou, Qilin</creator><creator>Pan, Mengling</creator><creator>Zhou, Wenjia</creator><creator>Ning, Zhijun</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-9130-3490</orcidid></search><sort><creationdate>202304</creationdate><title>Surface-Energy-Regulated Growth of α-Phase Cs 0.03 FA 0.97 PbI 3 for Highly Efficient and Stable Inverted Perovskite Solar Cells</title><author>Pan, Ting ; Zhou, Wei ; Wei, Qi ; Peng, Zijian ; Wang, Hao ; Jiang, Xianyuan ; Zang, Zihao ; Li, Hansheng ; Yu, Danni ; Zhou, Qilin ; Pan, Mengling ; Zhou, Wenjia ; Ning, Zhijun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1073-52614dda965fb2592eeb41d33096d9ae6f5079bcf79eb5f612492ccf0db15cda3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pan, Ting</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Wei, Qi</creatorcontrib><creatorcontrib>Peng, Zijian</creatorcontrib><creatorcontrib>Wang, Hao</creatorcontrib><creatorcontrib>Jiang, Xianyuan</creatorcontrib><creatorcontrib>Zang, Zihao</creatorcontrib><creatorcontrib>Li, Hansheng</creatorcontrib><creatorcontrib>Yu, Danni</creatorcontrib><creatorcontrib>Zhou, Qilin</creatorcontrib><creatorcontrib>Pan, Mengling</creatorcontrib><creatorcontrib>Zhou, Wenjia</creatorcontrib><creatorcontrib>Ning, Zhijun</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Advanced materials (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pan, Ting</au><au>Zhou, Wei</au><au>Wei, Qi</au><au>Peng, Zijian</au><au>Wang, Hao</au><au>Jiang, Xianyuan</au><au>Zang, Zihao</au><au>Li, Hansheng</au><au>Yu, Danni</au><au>Zhou, Qilin</au><au>Pan, Mengling</au><au>Zhou, Wenjia</au><au>Ning, Zhijun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Surface-Energy-Regulated Growth of α-Phase Cs 0.03 FA 0.97 PbI 3 for Highly Efficient and Stable Inverted Perovskite Solar Cells</atitle><jtitle>Advanced materials (Weinheim)</jtitle><addtitle>Adv Mater</addtitle><date>2023-04</date><risdate>2023</risdate><volume>35</volume><issue>15</issue><spage>e2208522</spage><pages>e2208522-</pages><issn>0935-9648</issn><eissn>1521-4095</eissn><abstract>Methylammonium (MA)-free formamidinium (FA)-dominated Cs
FA
PbI
is rising as the most promising candidate for highly efficient and stable perovskite solar cells. However, the growth of high-quality Cs
FA
PbI
black-phase perovskite structure without ion doping in the lattice remains a challenge. Herein, propeller-shaped halogenated tertiary ammonium is synthesized, showing high binding energy on the perovskite surface and large steric hindrance. This molecule can significantly reduce the barrier of high surface energy that suppresses the growth of the α-phase Cs
FA
PbI
structure. As a result, the α-phase structure can be formed at room temperature, which can further act as a seed for the growth of high-quality film. Solar cells based on the film show a record efficiency up to 23.6% for MA free Cs
FA
PbI
solar cells with inverted structure and excellent stability at 85 °C over 200 h.</abstract><cop>Germany</cop><pmid>36692303</pmid><doi>10.1002/adma.202208522</doi><orcidid>https://orcid.org/0000-0002-9130-3490</orcidid></addata></record> |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| title | Surface-Energy-Regulated Growth of α-Phase Cs 0.03 FA 0.97 PbI 3 for Highly Efficient and Stable Inverted Perovskite Solar Cells |
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