The interaction of poly (p-phenylenevinylene) with air
The exposure of poly(p‐phenylenevinylene), PPV, to air affects its performance in polymer‐based light‐emitting devices. An investigation is described in which exposure to air is demonstrated to give rise to reversible affects associated with the absorption of water vapor, leading to determinal chang...
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Veröffentlicht in: | Advanced materials (Weinheim) 1996-12, Vol.8 (12), p.971-974 |
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container_title | Advanced materials (Weinheim) |
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creator | Xing, Kezhao Fahlman, Mats Lögdlund, Michael dos Santos, Doni A. Parenté, Vincent Lazzaroni, Roberto Brédas, Jean-Luc Gymer, Richard W. Salaneck, William R. |
description | The exposure of poly(p‐phenylenevinylene), PPV, to air affects its performance in polymer‐based light‐emitting devices. An investigation is described in which exposure to air is demonstrated to give rise to reversible affects associated with the absorption of water vapor, leading to determinal changes in the outer electronic structure (see also the cover of this issue). In particular the resulting increase in torsion angle is shown to lead to a reduction in conjugation. A method of preparing clean PPV films is proposed. |
doi_str_mv | 10.1002/adma.19960081204 |
format | Article |
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An investigation is described in which exposure to air is demonstrated to give rise to reversible affects associated with the absorption of water vapor, leading to determinal changes in the outer electronic structure (see also the cover of this issue). In particular the resulting increase in torsion angle is shown to lead to a reduction in conjugation. A method of preparing clean PPV films is proposed.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.19960081204</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag GmbH</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; Surface properties</subject><ispartof>Advanced materials (Weinheim), 1996-12, Vol.8 (12), p.971-974</ispartof><rights>Copyright © 1996 Verlag GmbH & Co. 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source | Wiley Online Library Journals Frontfile Complete |
subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization Surface properties |
title | The interaction of poly (p-phenylenevinylene) with air |
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