The interaction of poly (p-phenylenevinylene) with air

The exposure of poly(p‐phenylenevinylene), PPV, to air affects its performance in polymer‐based light‐emitting devices. An investigation is described in which exposure to air is demonstrated to give rise to reversible affects associated with the absorption of water vapor, leading to determinal chang...

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Veröffentlicht in:Advanced materials (Weinheim) 1996-12, Vol.8 (12), p.971-974
Hauptverfasser: Xing, Kezhao, Fahlman, Mats, Lögdlund, Michael, dos Santos, Doni A., Parenté, Vincent, Lazzaroni, Roberto, Brédas, Jean-Luc, Gymer, Richard W., Salaneck, William R.
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container_end_page 974
container_issue 12
container_start_page 971
container_title Advanced materials (Weinheim)
container_volume 8
creator Xing, Kezhao
Fahlman, Mats
Lögdlund, Michael
dos Santos, Doni A.
Parenté, Vincent
Lazzaroni, Roberto
Brédas, Jean-Luc
Gymer, Richard W.
Salaneck, William R.
description The exposure of poly(p‐phenylenevinylene), PPV, to air affects its performance in polymer‐based light‐emitting devices. An investigation is described in which exposure to air is demonstrated to give rise to reversible affects associated with the absorption of water vapor, leading to determinal changes in the outer electronic structure (see also the cover of this issue). In particular the resulting increase in torsion angle is shown to lead to a reduction in conjugation. A method of preparing clean PPV films is proposed.
doi_str_mv 10.1002/adma.19960081204
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source Wiley Online Library Journals Frontfile Complete
subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Surface properties
title The interaction of poly (p-phenylenevinylene) with air
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