Amphiphilic dyes for nonlinear optics: Dependence of second harmonic generation on functional group substitution

Amphiphilic dyes for nonlinear optics: Dependence of second harmonic generation on functional group substitution

Communication: Orientation of chromophores by using the Langmuir‐Blodgett film‐prepration procedure, to a degree practically impossible to achieve by poling in polymer matrices in an electric field, has held to materials exhibiting the highest values of the second order susceptibility (χ(2)) yet kno...

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Veröffentlicht in:Advanced materials (Weinheim) 1991-01, Vol.3 (1), p.54-58
Hauptverfasser: Bubeck, Christoph, Laschewsky, André, Lupo, Donald, Neher, Dieter, Ottenbreit, Petra, Paulus, Wolfgang, Prass, Werner, Ringsdorf, Helmut, Wegner, Gerhard
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Sprache:eng
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Chemistry
Exact sciences and technology
General and physical chemistry
Solid-liquid interface
Surface physical chemistry
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container_end_page 58
container_issue 1
container_start_page 54
container_title Advanced materials (Weinheim)
container_volume 3
creator Bubeck, Christoph
Laschewsky, André
Lupo, Donald
Neher, Dieter
Ottenbreit, Petra
Paulus, Wolfgang
Prass, Werner
Ringsdorf, Helmut
Wegner, Gerhard
description Communication: Orientation of chromophores by using the Langmuir‐Blodgett film‐prepration procedure, to a degree practically impossible to achieve by poling in polymer matrices in an electric field, has held to materials exhibiting the highest values of the second order susceptibility (χ(2)) yet known. The effect of different functional groups in both phenylhydrazone and stryrylpyridinium compounds on both molecular nonlinearity and order in the films the factors which most strongly influence (χ(2)) has been investigated and a thioether substituent is found to increas (χ(2)) significantly.
doi_str_mv 10.1002/adma.19910030111
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subjects Chemistry
Exact sciences and technology
General and physical chemistry
Solid-liquid interface
Surface physical chemistry
title Amphiphilic dyes for nonlinear optics: Dependence of second harmonic generation on functional group substitution
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