Kinetical study of the condensation reaction of 2-furaldehyde and 2-furfurylidene methyl ketone. Solvent influence
The influence of solvent nature upon the formation rate of 2‐difurfurylidene ketone with the use of water, methanol, ethanol, and propanol as catalyst solvent was studied. It was verified that the reaction proceeds slowly in aqueous medium due to the low solubility of the reactants and intermediates...
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Veröffentlicht in: | Acta polymerica 1991-10, Vol.42 (10), p.520-522 |
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creator | De Los Rios, M. Diaz Planes, R. L. Cruz, B. H. Luna, N. L. |
description | The influence of solvent nature upon the formation rate of 2‐difurfurylidene ketone with the use of water, methanol, ethanol, and propanol as catalyst solvent was studied. It was verified that the reaction proceeds slowly in aqueous medium due to the low solubility of the reactants and intermediates.
Der Einfluß der Art des Lösungsmittels auf die Bildungsgeschwindigkeit von 2‐Difurfurylidenketon bei Verwendung von Wasser, Methanol, Ethanol und Propanol als Katalysatorlösungsmittel wurde untersucht. Es wurde gefunden, daß die Reaktion in wäßriger Lösung wegen der geringen Löslichkeit der Reaktanten und der Zwischenprodukte sehr langsam abläuft. |
doi_str_mv | 10.1002/actp.1991.010421011 |
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Der Einfluß der Art des Lösungsmittels auf die Bildungsgeschwindigkeit von 2‐Difurfurylidenketon bei Verwendung von Wasser, Methanol, Ethanol und Propanol als Katalysatorlösungsmittel wurde untersucht. Es wurde gefunden, daß die Reaktion in wäßriger Lösung wegen der geringen Löslichkeit der Reaktanten und der Zwischenprodukte sehr langsam abläuft.</description><identifier>ISSN: 0323-7648</identifier><identifier>EISSN: 1521-4044</identifier><identifier>DOI: 10.1002/actp.1991.010421011</identifier><identifier>CODEN: ACPODY</identifier><language>eng</language><publisher>Berlin: Akademie Verlag GmbH</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polycondensation ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Acta polymerica, 1991-10, Vol.42 (10), p.520-522</ispartof><rights>1991 Akademie Verlag GmbH, Berlin</rights><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2361-8772bc68372cdc08a734e6f2b3172a1476fafdcf37d32f4dbb30c8db8f4f8d473</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Factp.1991.010421011$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Factp.1991.010421011$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5016681$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>De Los Rios, M. Diaz</creatorcontrib><creatorcontrib>Planes, R. L.</creatorcontrib><creatorcontrib>Cruz, B. H.</creatorcontrib><creatorcontrib>Luna, N. L.</creatorcontrib><title>Kinetical study of the condensation reaction of 2-furaldehyde and 2-furfurylidene methyl ketone. Solvent influence</title><title>Acta polymerica</title><addtitle>Acta Polym</addtitle><description>The influence of solvent nature upon the formation rate of 2‐difurfurylidene ketone with the use of water, methanol, ethanol, and propanol as catalyst solvent was studied. It was verified that the reaction proceeds slowly in aqueous medium due to the low solubility of the reactants and intermediates.
Der Einfluß der Art des Lösungsmittels auf die Bildungsgeschwindigkeit von 2‐Difurfurylidenketon bei Verwendung von Wasser, Methanol, Ethanol und Propanol als Katalysatorlösungsmittel wurde untersucht. Es wurde gefunden, daß die Reaktion in wäßriger Lösung wegen der geringen Löslichkeit der Reaktanten und der Zwischenprodukte sehr langsam abläuft.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polycondensation</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0323-7648</issn><issn>1521-4044</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNqNkMtqHDEQRUWIIRPbX-CNFtn2RK-R5E3ADI5jbJLg906opRIju60eJE3i_vt002HIMlBQRVXde-EgdELJkhLCPltXt0t6ekqXhBLBKKH0HVrQFaONIEK8RwvCGW-UFPoD-ljKMyFES7ZaoHwVE9TobIdL3fkB9wHXDWDXJw-p2Br7hDOMAdMwHlkTdtl2HjaDB2yTnzdjDV0cJYBfoW6GDr9A7RMs8W3f_YJUcUyh20FycIQOgu0KHP_th-j-6_nd-ltz_ePicn123TjGJW20Uqx1UnPFnHdEW8UFyMBaThWzVCgZbPAucOU5C8K3LSdO-1YHEbQXih8iPvu63JeSIZhtjq82D4YSM2EzEzYzYTN7bKPq06za2jJSCdkmF8teuiJUSj29fZnffscOhv9xNmfru5__5jSzQSwV3vYGNr8YqbhamcfvF-bpiTxcqRtmHvgf5AuRkA</recordid><startdate>199110</startdate><enddate>199110</enddate><creator>De Los Rios, M. Diaz</creator><creator>Planes, R. L.</creator><creator>Cruz, B. H.</creator><creator>Luna, N. L.</creator><general>Akademie Verlag GmbH</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>199110</creationdate><title>Kinetical study of the condensation reaction of 2-furaldehyde and 2-furfurylidene methyl ketone. Solvent influence</title><author>De Los Rios, M. Diaz ; Planes, R. L. ; Cruz, B. H. ; Luna, N. L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2361-8772bc68372cdc08a734e6f2b3172a1476fafdcf37d32f4dbb30c8db8f4f8d473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1991</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polycondensation</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>De Los Rios, M. Diaz</creatorcontrib><creatorcontrib>Planes, R. L.</creatorcontrib><creatorcontrib>Cruz, B. H.</creatorcontrib><creatorcontrib>Luna, N. L.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Acta polymerica</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>De Los Rios, M. Diaz</au><au>Planes, R. L.</au><au>Cruz, B. H.</au><au>Luna, N. L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetical study of the condensation reaction of 2-furaldehyde and 2-furfurylidene methyl ketone. Solvent influence</atitle><jtitle>Acta polymerica</jtitle><addtitle>Acta Polym</addtitle><date>1991-10</date><risdate>1991</risdate><volume>42</volume><issue>10</issue><spage>520</spage><epage>522</epage><pages>520-522</pages><issn>0323-7648</issn><eissn>1521-4044</eissn><coden>ACPODY</coden><abstract>The influence of solvent nature upon the formation rate of 2‐difurfurylidene ketone with the use of water, methanol, ethanol, and propanol as catalyst solvent was studied. It was verified that the reaction proceeds slowly in aqueous medium due to the low solubility of the reactants and intermediates.
Der Einfluß der Art des Lösungsmittels auf die Bildungsgeschwindigkeit von 2‐Difurfurylidenketon bei Verwendung von Wasser, Methanol, Ethanol und Propanol als Katalysatorlösungsmittel wurde untersucht. Es wurde gefunden, daß die Reaktion in wäßriger Lösung wegen der geringen Löslichkeit der Reaktanten und der Zwischenprodukte sehr langsam abläuft.</abstract><cop>Berlin</cop><pub>Akademie Verlag GmbH</pub><doi>10.1002/actp.1991.010421011</doi><tpages>3</tpages></addata></record> |
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subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polycondensation Preparation, kinetics, thermodynamics, mechanism and catalysts |
title | Kinetical study of the condensation reaction of 2-furaldehyde and 2-furfurylidene methyl ketone. Solvent influence |
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