Potassium persulphate-cupric ion induced grafting of acrylonitrile to nylon 6 fibres
Polyamide 6‐acrylonitrile graft copolymers were prepared without formation of homopolymer by using an initiation system consisting of potassium persulphate, cupric ion and a surface active substance. The graft yield was determined in dependence on the concentration of cupric ion, persulphate and acr...
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| Veröffentlicht in: | Acta polymerica 1984-04, Vol.35 (4), p.321-324 |
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| container_end_page | 324 |
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| container_issue | 4 |
| container_start_page | 321 |
| container_title | Acta polymerica |
| container_volume | 35 |
| creator | Shalaby, S. E. El-Shahed, M. F. Heibeish, A. |
| description | Polyamide 6‐acrylonitrile graft copolymers were prepared without formation of homopolymer by using an initiation system consisting of potassium persulphate, cupric ion and a surface active substance. The graft yield was determined in dependence on the concentration of cupric ion, persulphate and acrylonitrile as well as time and temperature of polymerization. A mechanism of the grafting reaction is suggested.
Polyamid‐6‐Acrylnitril‐Pfropfcopolymere wurden unter Vermeidung der Bildung von Homopolymeren durch Verwendung eines Initiatorsystems aus Kaliumpersulfat, Cupfer(II)‐Ionen und einer oberflächenaktiven Substanz synthetisiert. Die Pfropfausbeute wurde in Abhängigkeit von der Konzentration der Cupfer(II)‐Ionen, des Persulfats und des Acrylnitrils sowie von der Polymerisationszeit und der Polymerisationstemperatur bestimmt. Ein möglicher Mechanismus der Pfropfungsreaktion wird vorgeschlagen. |
| doi_str_mv | 10.1002/actp.1984.010350415 |
| format | Article |
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Polyamid‐6‐Acrylnitril‐Pfropfcopolymere wurden unter Vermeidung der Bildung von Homopolymeren durch Verwendung eines Initiatorsystems aus Kaliumpersulfat, Cupfer(II)‐Ionen und einer oberflächenaktiven Substanz synthetisiert. Die Pfropfausbeute wurde in Abhängigkeit von der Konzentration der Cupfer(II)‐Ionen, des Persulfats und des Acrylnitrils sowie von der Polymerisationszeit und der Polymerisationstemperatur bestimmt. Ein möglicher Mechanismus der Pfropfungsreaktion wird vorgeschlagen.</description><identifier>ISSN: 0323-7648</identifier><identifier>EISSN: 1521-4044</identifier><identifier>DOI: 10.1002/actp.1984.010350415</identifier><identifier>CODEN: ACPODY</identifier><language>eng</language><publisher>Berlin: Akademie Verlag GmbH</publisher><subject>Applied sciences ; Exact sciences and technology ; Fibers and threads ; Forms of application and semi-finished materials ; Polymer industry, paints, wood ; Technology of polymers</subject><ispartof>Acta polymerica, 1984-04, Vol.35 (4), p.321-324</ispartof><rights>1984 Akademie Verlag GmbH, Berlin</rights><rights>1985 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2865-c3c33d045d8fefc433eaa8acd5e39f908f8208765a31916888f91a06e7a4208a3</citedby><cites>FETCH-LOGICAL-c2865-c3c33d045d8fefc433eaa8acd5e39f908f8208765a31916888f91a06e7a4208a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Factp.1984.010350415$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Factp.1984.010350415$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=9154094$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Shalaby, S. E.</creatorcontrib><creatorcontrib>El-Shahed, M. F.</creatorcontrib><creatorcontrib>Heibeish, A.</creatorcontrib><title>Potassium persulphate-cupric ion induced grafting of acrylonitrile to nylon 6 fibres</title><title>Acta polymerica</title><addtitle>Acta Polym</addtitle><description>Polyamide 6‐acrylonitrile graft copolymers were prepared without formation of homopolymer by using an initiation system consisting of potassium persulphate, cupric ion and a surface active substance. The graft yield was determined in dependence on the concentration of cupric ion, persulphate and acrylonitrile as well as time and temperature of polymerization. A mechanism of the grafting reaction is suggested.
Polyamid‐6‐Acrylnitril‐Pfropfcopolymere wurden unter Vermeidung der Bildung von Homopolymeren durch Verwendung eines Initiatorsystems aus Kaliumpersulfat, Cupfer(II)‐Ionen und einer oberflächenaktiven Substanz synthetisiert. Die Pfropfausbeute wurde in Abhängigkeit von der Konzentration der Cupfer(II)‐Ionen, des Persulfats und des Acrylnitrils sowie von der Polymerisationszeit und der Polymerisationstemperatur bestimmt. Ein möglicher Mechanismus der Pfropfungsreaktion wird vorgeschlagen.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Fibers and threads</subject><subject>Forms of application and semi-finished materials</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0323-7648</issn><issn>1521-4044</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><recordid>eNqNkEFPwzAMhSMEEmPwC7jkwLXDaZI2vSBNEwzQgCENcYxMmoxA11ZJJ9i_p9PQxJGTZfm9z_Yj5JzBiAGkl2i6dsQKJUbAgEsQTB6QAZMpSwQIcUgGwFOe5JlQx-Qkxg8AUFkqB2QxbzqM0a9XtLUhrqv2HTubmHUbvKG-qamvy7WxJV0GdJ2vl7RxFE3YVE3tu-ArS7uG1tuWZtT5t2DjKTlyWEV79luH5OXmejG5TWZP07vJeJaYVGUyMdxwXoKQpXLWGcG5RVRoSml54QpQTqWg8kwiZwXLlFKuYAiZzVH0A-RDwndcE5oYg3W6v3qFYaMZ6G0wehuM3gaj98H0roudq8VosHIBa-Pj3lowKaAQvexqJ_vqf9z8h6zHk8X8755kB_Cxs997AIZPneU8l_r1caoF5Gz6fM_1A_8BvDOF3w</recordid><startdate>198404</startdate><enddate>198404</enddate><creator>Shalaby, S. E.</creator><creator>El-Shahed, M. F.</creator><creator>Heibeish, A.</creator><general>Akademie Verlag GmbH</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>198404</creationdate><title>Potassium persulphate-cupric ion induced grafting of acrylonitrile to nylon 6 fibres</title><author>Shalaby, S. E. ; El-Shahed, M. F. ; Heibeish, A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2865-c3c33d045d8fefc433eaa8acd5e39f908f8208765a31916888f91a06e7a4208a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1984</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Fibers and threads</topic><topic>Forms of application and semi-finished materials</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shalaby, S. E.</creatorcontrib><creatorcontrib>El-Shahed, M. F.</creatorcontrib><creatorcontrib>Heibeish, A.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Acta polymerica</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shalaby, S. E.</au><au>El-Shahed, M. F.</au><au>Heibeish, A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Potassium persulphate-cupric ion induced grafting of acrylonitrile to nylon 6 fibres</atitle><jtitle>Acta polymerica</jtitle><addtitle>Acta Polym</addtitle><date>1984-04</date><risdate>1984</risdate><volume>35</volume><issue>4</issue><spage>321</spage><epage>324</epage><pages>321-324</pages><issn>0323-7648</issn><eissn>1521-4044</eissn><coden>ACPODY</coden><abstract>Polyamide 6‐acrylonitrile graft copolymers were prepared without formation of homopolymer by using an initiation system consisting of potassium persulphate, cupric ion and a surface active substance. The graft yield was determined in dependence on the concentration of cupric ion, persulphate and acrylonitrile as well as time and temperature of polymerization. A mechanism of the grafting reaction is suggested.
Polyamid‐6‐Acrylnitril‐Pfropfcopolymere wurden unter Vermeidung der Bildung von Homopolymeren durch Verwendung eines Initiatorsystems aus Kaliumpersulfat, Cupfer(II)‐Ionen und einer oberflächenaktiven Substanz synthetisiert. Die Pfropfausbeute wurde in Abhängigkeit von der Konzentration der Cupfer(II)‐Ionen, des Persulfats und des Acrylnitrils sowie von der Polymerisationszeit und der Polymerisationstemperatur bestimmt. Ein möglicher Mechanismus der Pfropfungsreaktion wird vorgeschlagen.</abstract><cop>Berlin</cop><pub>Akademie Verlag GmbH</pub><doi>10.1002/actp.1984.010350415</doi><tpages>4</tpages></addata></record> |
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| identifier | ISSN: 0323-7648 |
| ispartof | Acta polymerica, 1984-04, Vol.35 (4), p.321-324 |
| issn | 0323-7648 1521-4044 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_actp_1984_010350415 |
| source | Wiley Online Library - AutoHoldings Journals |
| subjects | Applied sciences Exact sciences and technology Fibers and threads Forms of application and semi-finished materials Polymer industry, paints, wood Technology of polymers |
| title | Potassium persulphate-cupric ion induced grafting of acrylonitrile to nylon 6 fibres |
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