Atmospheric chemistry of diazomethane - an experimental and theoretical study

The kinetics of the O 3 , OH and NO 3 radical reactions with diazomethane were studied in smog chamber experiments employing long-path FTIR and PTR-ToF-MS detection. The rate coefficients were determined to be k CH2NN+O3  = (3.2 ± 0.4) × 10 −17 and k CH2NN+OH  = (1.68 ± 0.12) × 10 −10 cm 3 molecule...

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Veröffentlicht in:	Molecular physics 2020-08, Vol.118 (15), p.e1718227
Hauptverfasser:	Antonsen, Simen Gjelseth, Bunkan, Arne Joakim C., Mikoviny, Tomas, Nielsen, Claus J., Stenstrøm, Yngve, Wisthaler, Armin, Zardin, Erika
Format:	Artikel
Sprache:	eng
Schlagworte:	amine photo-oxidation Atmospheric chemistry Diazomethane quantum chemistry Reaction kinetics reaction mechanism Smog
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