Tracking Structural Deactivation of H-Ferrierite Zeolite Catalyst During MTH with XRD
We used the methanol-to-hydrocarbon (MTH) reaction as a shape-selective model reaction to investigate coke formation in zeolite H-Ferrierite. Despite being a 2D topology in terms of channel propagation, the FER framework displays a lattice expansion in all three dimensions of space upon deactivation...
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| Veröffentlicht in: | Topics in catalysis 2023-10, Vol.66 (17-18), p.1418-1426 |
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| container_issue | 17-18 |
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| container_title | Topics in catalysis |
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| creator | Capel Berdiell, Izar Braghin, Giorgio Bruno Cordero-Lanzac, Tomás Beato, Pablo Lundegaard, Lars F. Wragg, David Bordiga, Silvia Svelle, Stian |
| description | We used the methanol-to-hydrocarbon (MTH) reaction as a shape-selective model reaction to investigate coke formation in zeolite H-Ferrierite. Despite being a 2D topology in terms of channel propagation, the FER framework displays a lattice expansion in all three dimensions of space upon deactivation. Therefore, the volume of the unit cell is an excellent X-Ray diffraction (XRD) descriptor for the catalyst deactivation. A model with dummy atoms added, also proved to be an accurate approach to measure the amount of internal coke and/or water inside the pore network correlated with thermogravimetric analysis results. While the catalyst deactivation of the H-Ferrerite during the MTH was fast, a comparably long induction period was observed. We were able to track such fast deactivation with the aforementioned descriptors by means of an
operando
XRD study by a standard laboratory diffractometer. |
| doi_str_mv | 10.1007/s11244-023-01780-0 |
| format | Article |
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operando
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operando
XRD study by a standard laboratory diffractometer.</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coke</subject><subject>Deactivation</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Original Paper</subject><subject>Pharmacy</subject><subject>Physical Chemistry</subject><subject>Thermogravimetric analysis</subject><subject>Topology</subject><subject>Unit cell</subject><subject>X-ray diffraction</subject><subject>Zeolites</subject><issn>1022-5528</issn><issn>1572-9028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>3HK</sourceid><recordid>eNp9kM1KAzEURoMoWKsv4CrgOpqfmSSzlNZaoSJoC-ImZNJEU8eZmmSUvr0zjuLOzb138X2HywHglOBzgrG4iITQLEOYMoSJkBjhPTAiuaCowFTudzemFOU5lYfgKMYNxpSIohiB1TJo8-rrZ_iQQmtSG3QFp1ab5D908k0NGwfnaGZD8Db4ZOGTbap-T3TS1S4mOG1D379dzuGnTy_w8X56DA6crqI9-dljsJpdLSdztLi7vplcLpBhUiZUUma4KY3mhq8pLtfOUs7zwhbUaUYya1guyRpL7rBjhRTSactLbYxwrI-MARy4JviYfK3qJmhFsMxpNwnPcRc5GyLb0Ly3Nia1adpQd18pKrkQXBYZ61L0F9TEGKxT2-DfdNh1GNUbVoNh1RlW34ZVj2ZDKW57Azb8of9pfQHfh3z6</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Capel Berdiell, Izar</creator><creator>Braghin, Giorgio Bruno</creator><creator>Cordero-Lanzac, Tomás</creator><creator>Beato, Pablo</creator><creator>Lundegaard, Lars F.</creator><creator>Wragg, David</creator><creator>Bordiga, Silvia</creator><creator>Svelle, Stian</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3HK</scope></search><sort><creationdate>20231001</creationdate><title>Tracking Structural Deactivation of H-Ferrierite Zeolite Catalyst During MTH with XRD</title><author>Capel Berdiell, Izar ; Braghin, Giorgio Bruno ; Cordero-Lanzac, Tomás ; Beato, Pablo ; Lundegaard, Lars F. ; Wragg, David ; Bordiga, Silvia ; Svelle, Stian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c388t-b23c6cbca6c6d20bdfe26659e92fa314ec3581d086f0f39878fae6bacc7f32fa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coke</topic><topic>Deactivation</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Original Paper</topic><topic>Pharmacy</topic><topic>Physical Chemistry</topic><topic>Thermogravimetric analysis</topic><topic>Topology</topic><topic>Unit cell</topic><topic>X-ray diffraction</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Capel Berdiell, Izar</creatorcontrib><creatorcontrib>Braghin, Giorgio Bruno</creatorcontrib><creatorcontrib>Cordero-Lanzac, Tomás</creatorcontrib><creatorcontrib>Beato, Pablo</creatorcontrib><creatorcontrib>Lundegaard, Lars F.</creatorcontrib><creatorcontrib>Wragg, David</creatorcontrib><creatorcontrib>Bordiga, Silvia</creatorcontrib><creatorcontrib>Svelle, Stian</creatorcontrib><collection>Springer Nature OA/Free Journals</collection><collection>CrossRef</collection><collection>NORA - Norwegian Open Research Archives</collection><jtitle>Topics in catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Capel Berdiell, Izar</au><au>Braghin, Giorgio Bruno</au><au>Cordero-Lanzac, Tomás</au><au>Beato, Pablo</au><au>Lundegaard, Lars F.</au><au>Wragg, David</au><au>Bordiga, Silvia</au><au>Svelle, Stian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tracking Structural Deactivation of H-Ferrierite Zeolite Catalyst During MTH with XRD</atitle><jtitle>Topics in catalysis</jtitle><stitle>Top Catal</stitle><date>2023-10-01</date><risdate>2023</risdate><volume>66</volume><issue>17-18</issue><spage>1418</spage><epage>1426</epage><pages>1418-1426</pages><issn>1022-5528</issn><eissn>1572-9028</eissn><abstract>We used the methanol-to-hydrocarbon (MTH) reaction as a shape-selective model reaction to investigate coke formation in zeolite H-Ferrierite. 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operando
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| subjects | Catalysis Catalysts Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Coke Deactivation Industrial Chemistry/Chemical Engineering Original Paper Pharmacy Physical Chemistry Thermogravimetric analysis Topology Unit cell X-ray diffraction Zeolites |
| title | Tracking Structural Deactivation of H-Ferrierite Zeolite Catalyst During MTH with XRD |
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