Characterization and Apparent Kinetics of Polymerization of 1-Decene Catalyzed by Boron Trifluoride/Alcohol System
Poly-α-olefin (PAO) synthetic oil is the base oil of high-quality lubricants, and has a huge market potential. We illustrate PAO synthesis by catalytic polymerization of 1-decene with a boron trifluoride (BF3)/alcohol system. Gas chromatography-mass spectrometry, proton nuclear magnetic resonance an...
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| Veröffentlicht in: | 中国炼油与石油化工：英文版 2017-09, Vol.19 (3), p.16-22 |
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| container_title | 中国炼油与石油化工：英文版 |
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| creator | Wang Sihan Wang Libo Liu Tong Ma Lili Huo Hongliang Wang Jian |
| description | Poly-α-olefin (PAO) synthetic oil is the base oil of high-quality lubricants, and has a huge market potential. We illustrate PAO synthesis by catalytic polymerization of 1-decene with a boron trifluoride (BF3)/alcohol system. Gas chromatography-mass spectrometry, proton nuclear magnetic resonance and 13C nuclear magnetic resonance analysis confirmed dimer, trimer and tetramer structures of PAO. Each component contained branched chains with a 1,2 insertion of a head-to-tail link; a 2,1 insertion of a tail-to-tail link and a methyl-containing linked structure. At a low conversion rate, the reaction rate was related directly with the reaction temperature and the catalyst/1-decene concentration. An apparent kinetic equation for PAO formation was determined during 1-decene polymerization. |
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We illustrate PAO synthesis by catalytic polymerization of 1-decene with a boron trifluoride (BF3)/alcohol system. Gas chromatography-mass spectrometry, proton nuclear magnetic resonance and 13C nuclear magnetic resonance analysis confirmed dimer, trimer and tetramer structures of PAO. Each component contained branched chains with a 1,2 insertion of a head-to-tail link; a 2,1 insertion of a tail-to-tail link and a methyl-containing linked structure. At a low conversion rate, the reaction rate was related directly with the reaction temperature and the catalyst/1-decene concentration. 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| identifier | ISSN: 1008-6234 |
| ispartof | 中国炼油与石油化工：英文版, 2017-09, Vol.19 (3), p.16-22 |
| issn | 1008-6234 |
| language | eng |
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| source | Alma/SFX Local Collection |
| subjects | 1-decene apparent boron kinetics poly-α-olefin product structure trifluoride |
| title | Characterization and Apparent Kinetics of Polymerization of 1-Decene Catalyzed by Boron Trifluoride/Alcohol System |
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