Synthesis and Immobilization of Polystyrene-b-Polyvinyltriethoxysilane Micelles

Synthesis and Immobilization of Polystyrene-b-Polyvinyltriethoxysilane Micelles

Diblock copolymers polystyrene-block-polyvinyltriethoxysilane（PS-b-PVTES） were synthesized via atom transfer radical polymerization（ATRP）, which self-assembled into spherical micelles in solvent of THF-methanol mixtures. The self-assembled micelles were immobilized by cross-linking reaction of VTES...

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Veröffentlicht in:武汉理工大学学报：材料科学英文版 2018-02, Vol.33 (1), p.221-225
Hauptverfasser: 朱赛赛, ZHU Hui, 夏茹, FENG Xiaoshuang, CHEN Peng, QIAN Jiasheng, CAO Ming, YANG Bin, MIAO Jibin, SU Lifen, SONG Changjiang
Format: Artikel
Sprache:eng
Schlagworte:
微粒
合成
混合溶剂
共聚物
原子转移
化学结构
THF
混合物
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container_issue 1
container_start_page 221
container_title 武汉理工大学学报：材料科学英文版
container_volume 33
creator 朱赛赛
ZHU Hui
夏茹
FENG Xiaoshuang
CHEN Peng
QIAN Jiasheng
CAO Ming
YANG Bin
MIAO Jibin
SU Lifen
SONG Changjiang
description Diblock copolymers polystyrene-block-polyvinyltriethoxysilane（PS-b-PVTES） were synthesized via atom transfer radical polymerization（ATRP）, which self-assembled into spherical micelles in solvent of THF-methanol mixtures. The self-assembled micelles were immobilized by cross-linking reaction of VTES in a shell layer of micelles. The chemical structures of block copolymers and morphology of micelles were characterized in detail. It was found that the size of immobilized micelles was strongly affected by the copolymer concentration, composition of mixture solvent, and block ratios.
doi_str_mv 10.1007/s11595-018-1809-9
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1993-0437
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source Alma/SFX Local Collection; SpringerLink Journals - AutoHoldings
subjects 微粒
合成
混合溶剂
共聚物
原子转移
化学结构
THF
混合物
title Synthesis and Immobilization of Polystyrene-b-Polyvinyltriethoxysilane Micelles
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