Synthesis of a Dichlorosilaimine Coordinated by an N-Heterocyclic Carbene from ArN（SiMe3）SiHCl2

Synthesis of a Dichlorosilaimine Coordinated by an N-Heterocyclic Carbene from ArN（SiMe3）SiHCl2

NHC-stabilized dichlorosilaimine ArN=Si（IiPr）Cl2 （2） （Ar=2,6-iPr2C6H3, IiPr=1,3-diisopropyl-4,5-dimeth- ylimidazol-2-ylidene） and disilane LSiHCl-SiCl2L （L=ArNSiMe3） （3） could be synthesized from the reaction of aminodichlorosilane ArN（SiMe3）SiHCl2 （1） with IiPr under different conditions. This repr...

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Veröffentlicht in:中国化学：英文版 2017, Vol.35 (4), p.401-404
1. Verfasser: Haiyan Cui Peng Teng Enbin Zhang Jiahao Lu Fan Zhang Meng Wu
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Sprache:eng
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Cl2
N-杂环卡宾
反应合成
氯硅烷
稳定
第一代
自主知识产权
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creator Haiyan Cui Peng Teng Enbin Zhang Jiahao Lu Fan Zhang Meng Wu
description NHC-stabilized dichlorosilaimine ArN=Si（IiPr）Cl2 （2） （Ar=2,6-iPr2C6H3, IiPr=1,3-diisopropyl-4,5-dimeth- ylimidazol-2-ylidene） and disilane LSiHCl-SiCl2L （L=ArNSiMe3） （3） could be synthesized from the reaction of aminodichlorosilane ArN（SiMe3）SiHCl2 （1） with IiPr under different conditions. This represents the first route to the generation of donor-stabilized dichlorosilaimine from substituted chlorosilane in the presence of an NHC via dehydrosilylation.
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This represents the first route to the generation of donor-stabilized dichlorosilaimine from substituted chlorosilane in the presence of an NHC via dehydrosilylation.</abstract></addata></record>
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subjects Cl2
N-杂环卡宾
反应合成
氯硅烷
稳定
第一代
自主知识产权
title Synthesis of a Dichlorosilaimine Coordinated by an N-Heterocyclic Carbene from ArN（SiMe3）SiHCl2
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