氟催化废弃硅基还原剂与CO_2还原转化反应（英文）

氟催化废弃硅基还原剂与CO_2还原转化反应（英文）

CO_2是最重要的可再生碳源之一.为了将CO_2转化为有用的有机化合物,我们研究了二种模型硅基＂废＂材料—乙硅烷和硅粉的反应活性.在这些反应中,氟盐的催化活性最高,在常压、在质子源水和硅基还原剂的存在下,CO_2可转化为甲酸.原位NMR和动力学分析表明,含氢硅烷和五配位的硅物种分别是反应中间物和活性物种....

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Veröffentlicht in:催化学报 2017, Vol.38 (3), p.434-439
1. Verfasser: Ken Motokura Masaki Naijo Sho Yamaguchi Akimitsu Miyaji Toshihide Baba
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Sprache:chi
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乙硅烷
二氧化碳
均相催化
氟
甲酸
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container_title 催化学报
container_volume 38
creator Ken Motokura Masaki Naijo Sho Yamaguchi Akimitsu Miyaji Toshihide Baba
description CO_2是最重要的可再生碳源之一.为了将CO_2转化为有用的有机化合物,我们研究了二种模型硅基＂废＂材料—乙硅烷和硅粉的反应活性.在这些反应中,氟盐的催化活性最高,在常压、在质子源水和硅基还原剂的存在下,CO_2可转化为甲酸.原位NMR和动力学分析表明,含氢硅烷和五配位的硅物种分别是反应中间物和活性物种.
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subjects 乙硅烷
二氧化碳
均相催化
氟
甲酸
title 氟催化废弃硅基还原剂与CO_2还原转化反应（英文）
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