Adsorption and Diffusion Behavior of Cl^- on Sputtering Fe–20Cr Nanocrystalline Thin Film in Acid Solution（pH = 2）
The adsorption and diffusion behavior of Cl~- on sputtering Fe-20 Cr nanocrystalline（NC） thin film compared with corresponding coarse crystalline（CC） alloy has been studied in HCl ＋ NaCl solution（pH = 2,[Cl~-]=0.1 mol/L） by electrochemical techniques,X-ray photoelectron spectroscopy（XPS） and the fir...
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| Veröffentlicht in: | 材料科学技术学报：英文版 2015, Vol.31 (12), p.1198-1206 |
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| container_title | 材料科学技术学报：英文版 |
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| creator | Bin Zhang Li Liu Tianshu Li Ying Li Mingkai Lei Fuhui Wang |
| description | The adsorption and diffusion behavior of Cl~- on sputtering Fe-20 Cr nanocrystalline（NC） thin film compared with corresponding coarse crystalline（CC） alloy has been studied in HCl ＋ NaCl solution（pH = 2,[Cl~-]=0.1 mol/L） by electrochemical techniques,X-ray photoelectron spectroscopy（XPS） and the firstprinciples calculations.The XPS results show that adsorption and diffusion of Cl~- in the passive film has been inhibited on NC thin film.Ultra-violet photoelectron spectroscopy（UPS） results show that the work function Φ s of NC thin film（4.7 eV） is higher than that of CC alloy（4.5 eV）.The theoretical calculations and valence electron structure analysis were used to understand the effect of nanocrystallization in this work. |
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| identifier | ISSN: 1005-0302 |
| ispartof | 材料科学技术学报：英文版, 2015, Vol.31 (12), p.1198-1206 |
| issn | 1005-0302 1941-1162 |
| language | eng |
| recordid | cdi_chongqing_primary_667620406 |
| source | Elsevier ScienceDirect Journals; Alma/SFX Local Collection |
| subjects | 20Cr X-射线光电子能谱 吸附 扩散行为 纳米薄膜 酸性溶液 |
| title | Adsorption and Diffusion Behavior of Cl^- on Sputtering Fe–20Cr Nanocrystalline Thin Film in Acid Solution（pH = 2） |
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