An air-stable supported Cu(I) catalyst for azide-alkyne click polymerization

An air-stable supported Cu(I) catalyst, CuI@PS-Phen, was designed and synthesized. CuI@PS-Phen can efficiently catalyze the click polymerization of diynes a and diazides b to produce soluble and thermally stable polytriazoles with high molecular weights (Mw up to 30800), and low copper residue conte...

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Veröffentlicht in:中国科学:化学英文版 2015 (11), p.1748-1752
1. Verfasser: Haiqiang Wu Wenhui Dong Zongtan Wang Bicheng Yao Ming Chen Jingzhi Sun Anjun Qin Ben Zhong Tang
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description An air-stable supported Cu(I) catalyst, CuI@PS-Phen, was designed and synthesized. CuI@PS-Phen can efficiently catalyze the click polymerization of diynes a and diazides b to produce soluble and thermally stable polytriazoles with high molecular weights (Mw up to 30800), and low copper residue content (down to 190 ppm) in high yields (up to 94.2%) under mild reaction conditions without the exclusion of oxygen.
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source Alma/SFX Local Collection; SpringerLink Journals - AutoHoldings; ProQuest Central
subjects phen
反应条件
叠氮
热稳定
空气
聚合催化剂
负载
title An air-stable supported Cu(I) catalyst for azide-alkyne click polymerization
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