Aliphatic Thermoplastic Poly(ether urethane)s Having LongPEG Sequences Synthesized through a Non-isocyanate Route

A non-isocyanate route for synthesizing thermoplastic polyurethanes with excellent thermal and mechanical properties was described. Melt transurethane polycondensation of 1,6-bis(hydroxyethyloxy carbonyl amino)hexane with four poly(ethylene glycol)s (PEGs), i.e. PEG400, PEG600, PEG1000, or PEG1500,...

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Veröffentlicht in:高分子科学:英文版 2015 (6), p.880-889
1. Verfasser: Yong Deng Su-qing Li Jing-bo Zhao Zhi-yuan Zhang Jun-ying Zhang Wan-tai Yang
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description A non-isocyanate route for synthesizing thermoplastic polyurethanes with excellent thermal and mechanical properties was described. Melt transurethane polycondensation of 1,6-bis(hydroxyethyloxy carbonyl amino)hexane with four poly(ethylene glycol)s (PEGs), i.e. PEG400, PEG600, PEG1000, or PEG1500, was conducted at different molar ratios. A series of thermoplastic poly(ether urethane)s (TPEUs) with long PEG sequences were prepared. The TPEUs were characterized via gel permeation chromatography, FTIR, 1H-NMR, differential scanning calorimetry, thermogravimetric analysis, wide-angle X-ray scattering, and tensile tests. The TPEUs exhibit Tg between 12.4 ℃ and -40.4 ℃, Tm of up to 149.8 ℃, and initial decomposition temperature over 239.4 ℃. The tensile strength of the TPEUs reaches 38.39 MPa with a strain at break of 852.92%.
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subjects PEG400
PEG600
凝胶渗透色谱法
合成路线
差示扫描量热法
序列
异氰酸酯
热塑性聚氨酯
title Aliphatic Thermoplastic Poly(ether urethane)s Having LongPEG Sequences Synthesized through a Non-isocyanate Route
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