Cu(Ⅱ) Complex/Multiwall Carbon Nanotube Modified Electrode for the Determination of Ascorbic Acid
A sensitive and selective method for the determination of ascorbic acid(AA) using [Cu(phen)2]2+/multiwalled carbon nanotubes modified glassy carbon electrode was developed. Electrochemical behavior and surface characteristics of the modified electrode were studied using scanning electrode microscopy...
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Veröffentlicht in: | 武汉理工大学学报:材料科学英文版 2015 (2), p.412-415 |
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container_title | 武汉理工大学学报:材料科学英文版 |
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creator | 李小雨 李曦 XIONG Yan LIU Xin DONG Yulin LIU Peng |
description | A sensitive and selective method for the determination of ascorbic acid(AA) using [Cu(phen)2]2+/multiwalled carbon nanotubes modified glassy carbon electrode was developed. Electrochemical behavior and surface characteristics of the modified electrode were studied using scanning electrode microscopy(SEM), electrochemical impedance spectroscopy(EIS) and cyclic voltammetry(CV). The experimental results showed that the modified electrode enhanced the electrochemical response of AA and exhibited good analytical performance for AA determination from 10 to 1 042 ?mol/L with a low detection limit of 9.67μmol/L(S/N=3). The modified electrode was also applied to the determination of AA in the Vitamin tablets and showed good recovery. |
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Electrochemical behavior and surface characteristics of the modified electrode were studied using scanning electrode microscopy(SEM), electrochemical impedance spectroscopy(EIS) and cyclic voltammetry(CV). The experimental results showed that the modified electrode enhanced the electrochemical response of AA and exhibited good analytical performance for AA determination from 10 to 1 042 ?mol/L with a low detection limit of 9.67μmol/L(S/N=3). The modified electrode was also applied to the determination of AA in the Vitamin tablets and showed good recovery.</description><identifier>ISSN: 1000-2413</identifier><identifier>EISSN: 1993-0437</identifier><language>eng</language><subject>修饰玻碳电极 ; 复合 ; 多壁碳纳米管修饰电极 ; 抗坏血酸 ; 测定 ; 电化学行为 ; 电化学阻抗谱 ; 铜</subject><ispartof>武汉理工大学学报:材料科学英文版, 2015 (2), p.412-415</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/84253X/84253X.jpg</thumbnail><link.rule.ids>314,780,784,4022</link.rule.ids></links><search><creatorcontrib>李小雨 李曦 XIONG Yan LIU Xin DONG Yulin LIU Peng</creatorcontrib><title>Cu(Ⅱ) Complex/Multiwall Carbon Nanotube Modified Electrode for the Determination of Ascorbic Acid</title><title>武汉理工大学学报:材料科学英文版</title><addtitle>Journal of Wuhan University of Technology. 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subjects | 修饰玻碳电极 复合 多壁碳纳米管修饰电极 抗坏血酸 测定 电化学行为 电化学阻抗谱 铜 |
title | Cu(Ⅱ) Complex/Multiwall Carbon Nanotube Modified Electrode for the Determination of Ascorbic Acid |
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