Sr3Bi(PO4)3:Eu^2+ Luminescence, Concentration Quenching and Crystallographic Sites

A blue emitting phosphor Sr3Bi(PO4)3:Eu2+ is synthesized luminescent property is investigated. Sr3Bi(PO4 )3 :Eu^2+ can by a high-temperature solid state method, and its create blue emission under the 332 radiation excitation, and the prominent luminescence in blue (423nm) due to the 4fSd^1→4f^7 tran...

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Veröffentlicht in:中国物理快报:英文版 2014 (7), p.73-76
1. Verfasser: 高少杰 李婷 张子才 李盼来 王志军 杨志平
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description A blue emitting phosphor Sr3Bi(PO4)3:Eu2+ is synthesized luminescent property is investigated. Sr3Bi(PO4 )3 :Eu^2+ can by a high-temperature solid state method, and its create blue emission under the 332 radiation excitation, and the prominent luminescence in blue (423nm) due to the 4fSd^1→4f^7 transition of the Eu^2+ ion. The crystallographic sites of the Eu^2+ ion in Sr3Bi(PO4)3 are analyzed, and the 420 and 440 nm emission peaks of the Eu^2+ ion are assigned to the nine-coordination and eight-coordination, respectively. The emission intensity of Sr3Bi(PO4)3:Eu^2+ is influenced by the Eu^2+ doping content, and the concentration quenching effect is observed. The quenching mechanism is the dipole-dipole interaction, and the critical distance of energy transfer is calculated by the concentration quenching method to be approximately 1.72nm.
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subjects 偶极相互作用
发光强度
发光特性
晶位
浓度猝灭
蓝色发光
蓝色荧光粉
title Sr3Bi(PO4)3:Eu^2+ Luminescence, Concentration Quenching and Crystallographic Sites
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