Preparation and characterization of Er3＋-Yb3＋-Ce3＋ co-doped transparent glass ceramic containing nano Cas（PO4）3F crystals
A transparent glass ceramic tri-doped with Ce3＋/Er3＋/yb3＋ was fabricated by the high-temperature melting technique and following heat-treatment. X-ray diffraction and transmission electron microscope results demonstrated that Cas（PO4）3F（FAP） nanocrystals, possessed with preferable emission performan...
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| Veröffentlicht in: | 中国稀土学报：英文版 2013, Vol.31 (4), p.400-404 |
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| container_title | 中国稀土学报：英文版 |
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| creator | 李永进 宋志国 李臣 邱建备 杨正文 尹兆益 杨勇 万荣华 王齐 |
| description | A transparent glass ceramic tri-doped with Ce3＋/Er3＋/yb3＋ was fabricated by the high-temperature melting technique and following heat-treatment. X-ray diffraction and transmission electron microscope results demonstrated that Cas（PO4）3F（FAP） nanocrystals, possessed with preferable emission performances for the 1.54 μm transition for doping Er3＋, were homogeneously pre- cipitated among the glass matrix with a mean size of 30 rim. Addition of Ce3＋ greatly enhanced 1.54 ~tm fluorescence of Er3＋ by the cross relaxation energy transfer between Er3＋ and Ce3＋. Meanwhile, incorporation of Ce3＋ dramatically decreased the visible upcon- version emission intensity of glass ceramic than that of glass, suggesting that Ce3＋ might incorporate into the FAP nanocrystals. The properties of this transparent glass ceramic showed the potential application as an efficient 980 nm pumped infrared laser medium. |
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X-ray diffraction and transmission electron microscope results demonstrated that Cas（PO4）3F（FAP） nanocrystals, possessed with preferable emission performances for the 1.54 μm transition for doping Er3＋, were homogeneously pre- cipitated among the glass matrix with a mean size of 30 rim. Addition of Ce3＋ greatly enhanced 1.54 ~tm fluorescence of Er3＋ by the cross relaxation energy transfer between Er3＋ and Ce3＋. Meanwhile, incorporation of Ce3＋ dramatically decreased the visible upcon- version emission intensity of glass ceramic than that of glass, suggesting that Ce3＋ might incorporate into the FAP nanocrystals. 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| ispartof | 中国稀土学报：英文版, 2013, Vol.31 (4), p.400-404 |
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| source | Elsevier ScienceDirect Journals; Alma/SFX Local Collection |
| subjects | CAS 制备 排放性能 玻璃陶瓷 纳米晶体 表征 透明玻璃 铒镱共掺 |
| title | Preparation and characterization of Er3＋-Yb3＋-Ce3＋ co-doped transparent glass ceramic containing nano Cas（PO4）3F crystals |
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