Sorption of Am(III) on Na-bentonite: Effect of pH, ionic strength, temperature and humic acid
Sorption of Am(III) on Na-bentonite as a function of contact time, pH, ionic strength, humic acid (HA) and temperature was investigated under ambient conditions. The results showed that the sorption was strongly dependent on pH and ionic strength. Am(III) sorption Can be described well by pseudo-sec...
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Veröffentlicht in: | 中国化学快报:英文版 2012, Vol.23 (10), p.1189-1192 |
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description | Sorption of Am(III) on Na-bentonite as a function of contact time, pH, ionic strength, humic acid (HA) and temperature was investigated under ambient conditions. The results showed that the sorption was strongly dependent on pH and ionic strength. Am(III) sorption Can be described well by pseudo-second-order model. The presence of HA takes a positive effect at low pH; but a negative influence under high pH range. Enthalpy, entropy and Gibbs free energy (i.e., △H0, △S0 and △G0) calculated from sorption isotherms suggested that sorption process of Am(III) was spontaneous and endothermic. |
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The results showed that the sorption was strongly dependent on pH and ionic strength. Am(III) sorption Can be described well by pseudo-second-order model. The presence of HA takes a positive effect at low pH; but a negative influence under high pH range. Enthalpy, entropy and Gibbs free energy (i.e., △H0, △S0 and △G0) calculated from sorption isotherms suggested that sorption process of Am(III) was spontaneous and endothermic.</description><identifier>ISSN: 1001-8417</identifier><identifier>EISSN: 1878-5964</identifier><language>eng</language><subject>III ; pH值 ; 吸附等温线 ; 温度 ; 离子强度 ; 腐殖酸 ; 钠基膨润土</subject><ispartof>中国化学快报:英文版, 2012, Vol.23 (10), p.1189-1192</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/84039X/84039X.jpg</thumbnail><link.rule.ids>314,780,784,4024</link.rule.ids></links><search><creatorcontrib>Tao Yu Wang Suo Wu Qiao Hui Fan</creatorcontrib><title>Sorption of Am(III) on Na-bentonite: Effect of pH, ionic strength, temperature and humic acid</title><title>中国化学快报:英文版</title><addtitle>Chinese Chemical Letters</addtitle><description>Sorption of Am(III) on Na-bentonite as a function of contact time, pH, ionic strength, humic acid (HA) and temperature was investigated under ambient conditions. The results showed that the sorption was strongly dependent on pH and ionic strength. Am(III) sorption Can be described well by pseudo-second-order model. The presence of HA takes a positive effect at low pH; but a negative influence under high pH range. Enthalpy, entropy and Gibbs free energy (i.e., △H0, △S0 and △G0) calculated from sorption isotherms suggested that sorption process of Am(III) was spontaneous and endothermic.</description><subject>III</subject><subject>pH值</subject><subject>吸附等温线</subject><subject>温度</subject><subject>离子强度</subject><subject>腐殖酸</subject><subject>钠基膨润土</subject><issn>1001-8417</issn><issn>1878-5964</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqNi0sOgjAYhBujifi4w-8eErA86tIYjGzc6J7UUqBGWixl4Q30Cp6FO3EFMfEArmYy3zcjZHkkIk6wCf3x0F3Xc4jvRVM0a5qr664JwaGF2Enp2gglQeWwrfrumSRJ371gWI7UuXBplBSG990b4jznzHzF-mDD8BEMGqO5LExpg-FVzTU1reZAZQZlWw2cMpEt0CSnt4YvfzlHq3183h0cVipZ3IUs0lqLiupH6uMIkxAH-B_nAyzcSCk</recordid><startdate>2012</startdate><enddate>2012</enddate><creator>Tao Yu Wang Suo Wu Qiao Hui Fan</creator><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope></search><sort><creationdate>2012</creationdate><title>Sorption of Am(III) on Na-bentonite: Effect of pH, ionic strength, temperature and humic acid</title><author>Tao Yu Wang Suo Wu Qiao Hui Fan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-chongqing_primary_437386353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>III</topic><topic>pH值</topic><topic>吸附等温线</topic><topic>温度</topic><topic>离子强度</topic><topic>腐殖酸</topic><topic>钠基膨润土</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tao Yu Wang Suo Wu Qiao Hui Fan</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><jtitle>中国化学快报:英文版</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tao Yu Wang Suo Wu Qiao Hui Fan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sorption of Am(III) on Na-bentonite: Effect of pH, ionic strength, temperature and humic acid</atitle><jtitle>中国化学快报:英文版</jtitle><addtitle>Chinese Chemical Letters</addtitle><date>2012</date><risdate>2012</risdate><volume>23</volume><issue>10</issue><spage>1189</spage><epage>1192</epage><pages>1189-1192</pages><issn>1001-8417</issn><eissn>1878-5964</eissn><abstract>Sorption of Am(III) on Na-bentonite as a function of contact time, pH, ionic strength, humic acid (HA) and temperature was investigated under ambient conditions. The results showed that the sorption was strongly dependent on pH and ionic strength. Am(III) sorption Can be described well by pseudo-second-order model. The presence of HA takes a positive effect at low pH; but a negative influence under high pH range. Enthalpy, entropy and Gibbs free energy (i.e., △H0, △S0 and △G0) calculated from sorption isotherms suggested that sorption process of Am(III) was spontaneous and endothermic.</abstract></addata></record> |
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source | Elsevier ScienceDirect Journals Complete; Alma/SFX Local Collection |
subjects | III pH值 吸附等温线 温度 离子强度 腐殖酸 钠基膨润土 |
title | Sorption of Am(III) on Na-bentonite: Effect of pH, ionic strength, temperature and humic acid |
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