Synthesis and spectral characteristics of La2MoO6:Ln3+ (Ln=Eu, Sm, Dy, Pr, Tb) polycrystals
The novel phosphors of La2MoO6 activated with the trivalent rare earth Ln3+ (Ln=Eu, Sm, Dy, Pr, Tb) ions were synthesized by solid state reactions at high temperature in air atmosphere, and their phase impurities and luminescent properties were studied. The photolu- minescence (PL) excitation and em...
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Veröffentlicht in: | 中国稀土学报:英文版 2012, Vol.30 (9), p.866-870 |
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description | The novel phosphors of La2MoO6 activated with the trivalent rare earth Ln3+ (Ln=Eu, Sm, Dy, Pr, Tb) ions were synthesized by solid state reactions at high temperature in air atmosphere, and their phase impurities and luminescent properties were studied. The photolu- minescence (PL) excitation and emission spectra, and decay curves were employed to study their luminescence properties. The lifetimes of the characteristic emissions from Ln3+ ions were in the order of millisecond except Pr3+ ions. (LaEu1-x)2MoO6 was a promising phosphor for practical application and the optimum concentration was x=0.075. The concentration quenching mechanism of Eu3+ was also discussed by theoretical fitting using Burshtein model. |
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The photolu- minescence (PL) excitation and emission spectra, and decay curves were employed to study their luminescence properties. The lifetimes of the characteristic emissions from Ln3+ ions were in the order of millisecond except Pr3+ ions. (LaEu1-x)2MoO6 was a promising phosphor for practical application and the optimum concentration was x=0.075. 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The photolu- minescence (PL) excitation and emission spectra, and decay curves were employed to study their luminescence properties. The lifetimes of the characteristic emissions from Ln3+ ions were in the order of millisecond except Pr3+ ions. (LaEu1-x)2MoO6 was a promising phosphor for practical application and the optimum concentration was x=0.075. 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The photolu- minescence (PL) excitation and emission spectra, and decay curves were employed to study their luminescence properties. The lifetimes of the characteristic emissions from Ln3+ ions were in the order of millisecond except Pr3+ ions. (LaEu1-x)2MoO6 was a promising phosphor for practical application and the optimum concentration was x=0.075. The concentration quenching mechanism of Eu3+ was also discussed by theoretical fitting using Burshtein model.</abstract></addata></record> |
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source | Elsevier ScienceDirect Journals; Alma/SFX Local Collection |
subjects | 光谱特性 反应合成 多晶 荧光激发光谱 钐 铕 镧系离子 |
title | Synthesis and spectral characteristics of La2MoO6:Ln3+ (Ln=Eu, Sm, Dy, Pr, Tb) polycrystals |
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