Structural, Sintering and Electrical Properties of Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) Oxides

The perovskite Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides were synthesized via the citrate gel method. The perovskite forming of the Lao.6Sr0.4CrxFel-xO3-δ (x=0.10, 0.20) oxides were studied by ther- mogravimetric analysis (TG), differential scanning calorimetry (DSC), and X-ray diffracti...

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Veröffentlicht in:材料科学技术学报:英文版 2012, Vol.28 (7), p.654-660
1. Verfasser: LinlinZhu Jong Pyo Kim Sou Hwan Son Jung Hoon Park
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description The perovskite Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides were synthesized via the citrate gel method. The perovskite forming of the Lao.6Sr0.4CrxFel-xO3-δ (x=0.10, 0.20) oxides were studied by ther- mogravimetric analysis (TG), differential scanning calorimetry (DSC), and X-ray diffraction (XRD). Structural and chemical stability under H2-containing helium atmospheres of Lao.6Sro.4CrxFel-xO3-δ (x=0.10, 0.20) were investigated by TG and XRD. The sintering microstructures of the perovskite Lao.6Sr0.4Cr2Fel-xO3-δ (x--0.10, 0.20) ceramics were investigated by scanning electron microscopy (SEM), and the electrical conduc- tivities of both oxide ceramics were also measured up to 900℃. The results demonstrated that the chemical stability of the Co-free Lao.oSro.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides was significantly improved compared to the Co-containing Lao.6Sr0.4C00.2Fe0.8O3-δ and Ba0.5Sr0.5Co0.8Fe0.2O3-δ oxides. The incorporation of Cr cations in the B-site of the pervoskite oxides resulted in the improved structural and chemical stability of the as-synthesized Lao.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides.
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The incorporation of Cr cations in the B-site of the pervoskite oxides resulted in the improved structural and chemical stability of the as-synthesized Lao.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides.</abstract></addata></record>
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subjects Cr掺杂
化学稳定性
差示扫描量热法
微观结构
氧化物陶瓷
烧结
电性能
钙钛矿氧化物
title Structural, Sintering and Electrical Properties of Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) Oxides
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