Structural, Sintering and Electrical Properties of Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) Oxides
The perovskite Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides were synthesized via the citrate gel method. The perovskite forming of the Lao.6Sr0.4CrxFel-xO3-δ (x=0.10, 0.20) oxides were studied by ther- mogravimetric analysis (TG), differential scanning calorimetry (DSC), and X-ray diffracti...
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description | The perovskite Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides were synthesized via the citrate gel method. The perovskite forming of the Lao.6Sr0.4CrxFel-xO3-δ (x=0.10, 0.20) oxides were studied by ther- mogravimetric analysis (TG), differential scanning calorimetry (DSC), and X-ray diffraction (XRD). Structural and chemical stability under H2-containing helium atmospheres of Lao.6Sro.4CrxFel-xO3-δ (x=0.10, 0.20) were investigated by TG and XRD. The sintering microstructures of the perovskite Lao.6Sr0.4Cr2Fel-xO3-δ (x--0.10, 0.20) ceramics were investigated by scanning electron microscopy (SEM), and the electrical conduc- tivities of both oxide ceramics were also measured up to 900℃. The results demonstrated that the chemical stability of the Co-free Lao.oSro.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides was significantly improved compared to the Co-containing Lao.6Sr0.4C00.2Fe0.8O3-δ and Ba0.5Sr0.5Co0.8Fe0.2O3-δ oxides. The incorporation of Cr cations in the B-site of the pervoskite oxides resulted in the improved structural and chemical stability of the as-synthesized Lao.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides. |
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The perovskite forming of the Lao.6Sr0.4CrxFel-xO3-δ (x=0.10, 0.20) oxides were studied by ther- mogravimetric analysis (TG), differential scanning calorimetry (DSC), and X-ray diffraction (XRD). Structural and chemical stability under H2-containing helium atmospheres of Lao.6Sro.4CrxFel-xO3-δ (x=0.10, 0.20) were investigated by TG and XRD. The sintering microstructures of the perovskite Lao.6Sr0.4Cr2Fel-xO3-δ (x--0.10, 0.20) ceramics were investigated by scanning electron microscopy (SEM), and the electrical conduc- tivities of both oxide ceramics were also measured up to 900℃. The results demonstrated that the chemical stability of the Co-free Lao.oSro.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides was significantly improved compared to the Co-containing Lao.6Sr0.4C00.2Fe0.8O3-δ and Ba0.5Sr0.5Co0.8Fe0.2O3-δ oxides. The incorporation of Cr cations in the B-site of the pervoskite oxides resulted in the improved structural and chemical stability of the as-synthesized Lao.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides.</description><identifier>ISSN: 1005-0302</identifier><identifier>EISSN: 1941-1162</identifier><language>eng</language><subject>Cr掺杂 ; 化学稳定性 ; 差示扫描量热法 ; 微观结构 ; 氧化物陶瓷 ; 烧结 ; 电性能 ; 钙钛矿氧化物</subject><ispartof>材料科学技术学报:英文版, 2012, Vol.28 (7), p.654-660</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/84252X/84252X.jpg</thumbnail><link.rule.ids>314,780,784,4024</link.rule.ids></links><search><creatorcontrib>LinlinZhu Jong Pyo Kim Sou Hwan Son Jung Hoon Park</creatorcontrib><title>Structural, Sintering and Electrical Properties of Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) Oxides</title><title>材料科学技术学报:英文版</title><addtitle>Journal of Materials Science & Technology</addtitle><description>The perovskite Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides were synthesized via the citrate gel method. The perovskite forming of the Lao.6Sr0.4CrxFel-xO3-δ (x=0.10, 0.20) oxides were studied by ther- mogravimetric analysis (TG), differential scanning calorimetry (DSC), and X-ray diffraction (XRD). Structural and chemical stability under H2-containing helium atmospheres of Lao.6Sro.4CrxFel-xO3-δ (x=0.10, 0.20) were investigated by TG and XRD. The sintering microstructures of the perovskite Lao.6Sr0.4Cr2Fel-xO3-δ (x--0.10, 0.20) ceramics were investigated by scanning electron microscopy (SEM), and the electrical conduc- tivities of both oxide ceramics were also measured up to 900℃. The results demonstrated that the chemical stability of the Co-free Lao.oSro.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides was significantly improved compared to the Co-containing Lao.6Sr0.4C00.2Fe0.8O3-δ and Ba0.5Sr0.5Co0.8Fe0.2O3-δ oxides. The incorporation of Cr cations in the B-site of the pervoskite oxides resulted in the improved structural and chemical stability of the as-synthesized Lao.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides.</description><subject>Cr掺杂</subject><subject>化学稳定性</subject><subject>差示扫描量热法</subject><subject>微观结构</subject><subject>氧化物陶瓷</subject><subject>烧结</subject><subject>电性能</subject><subject>钙钛矿氧化物</subject><issn>1005-0302</issn><issn>1941-1162</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqNjUsKwjAURYMo-N3Dc27KS1q1DhwVxYGgUOcS2qiR2upLhLoD3Y9D1-BW3IIduABH9xw4cGusJSaB4EKMZL1ixCFHH2WTta09IvrjYRi22Cl2dE3clVQ2gNjkTpPJ96DyFGaZThyZRGWwpuKsyRltodhBRDytPIWlQm8UE3pBROVcC16ufP5-wud1L6foCRwAehI_rwesSpNq22WNncqs7v22w_rz2SZa8ORQ5PtL9bw9kzkpum0DGQoRyrH_T_MFKQpIYg</recordid><startdate>2012</startdate><enddate>2012</enddate><creator>LinlinZhu Jong Pyo Kim Sou Hwan Son Jung Hoon Park</creator><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W92</scope><scope>~WA</scope></search><sort><creationdate>2012</creationdate><title>Structural, Sintering and Electrical Properties of Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) Oxides</title><author>LinlinZhu Jong Pyo Kim Sou Hwan Son Jung Hoon Park</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-chongqing_primary_428118273</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Cr掺杂</topic><topic>化学稳定性</topic><topic>差示扫描量热法</topic><topic>微观结构</topic><topic>氧化物陶瓷</topic><topic>烧结</topic><topic>电性能</topic><topic>钙钛矿氧化物</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>LinlinZhu Jong Pyo Kim Sou Hwan Son Jung Hoon Park</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库-工程技术</collection><collection>中文科技期刊数据库- 镜像站点</collection><jtitle>材料科学技术学报:英文版</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>LinlinZhu Jong Pyo Kim Sou Hwan Son Jung Hoon Park</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural, Sintering and Electrical Properties of Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) Oxides</atitle><jtitle>材料科学技术学报:英文版</jtitle><addtitle>Journal of Materials Science & Technology</addtitle><date>2012</date><risdate>2012</risdate><volume>28</volume><issue>7</issue><spage>654</spage><epage>660</epage><pages>654-660</pages><issn>1005-0302</issn><eissn>1941-1162</eissn><abstract>The perovskite Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides were synthesized via the citrate gel method. The perovskite forming of the Lao.6Sr0.4CrxFel-xO3-δ (x=0.10, 0.20) oxides were studied by ther- mogravimetric analysis (TG), differential scanning calorimetry (DSC), and X-ray diffraction (XRD). Structural and chemical stability under H2-containing helium atmospheres of Lao.6Sro.4CrxFel-xO3-δ (x=0.10, 0.20) were investigated by TG and XRD. The sintering microstructures of the perovskite Lao.6Sr0.4Cr2Fel-xO3-δ (x--0.10, 0.20) ceramics were investigated by scanning electron microscopy (SEM), and the electrical conduc- tivities of both oxide ceramics were also measured up to 900℃. The results demonstrated that the chemical stability of the Co-free Lao.oSro.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides was significantly improved compared to the Co-containing Lao.6Sr0.4C00.2Fe0.8O3-δ and Ba0.5Sr0.5Co0.8Fe0.2O3-δ oxides. The incorporation of Cr cations in the B-site of the pervoskite oxides resulted in the improved structural and chemical stability of the as-synthesized Lao.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) oxides.</abstract></addata></record> |
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subjects | Cr掺杂 化学稳定性 差示扫描量热法 微观结构 氧化物陶瓷 烧结 电性能 钙钛矿氧化物 |
title | Structural, Sintering and Electrical Properties of Cr-doped La0.6Sr0.4CrxFe1-xO3-δ (x=0.10, 0.20) Oxides |
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